ISSN 0253-2778

CN 34-1054/N

Open AccessOpen Access JUSTC Invited Reviews

Three-dimensional array materials for electrocatalytic water splitting

Cite this:
https://doi.org/10.52396/JUST-2021-0045
  • Received Date: 06 February 2021
  • Rev Recd Date: 22 February 2021
  • Publish Date: 28 February 2021
  • Hydrogen energy is considered to be one of the clean energy sources most likely to alternate fossil fuels. The exploration of catalytic materials suitable for electrocatalytic water splitting to produce hydrogen has become an important subject in the field of water electrolysis. Limited to the phenomena of easy stacking of nano-powder materials and poor conductivity during the catalytic reaction, the combination of nano-active materials and conductive substrates to construct three-dimensional (3D) array electrodes with open porous structures has become a research hotspot. This article first summarizes the advantages of 3D array electrodes for water electrolysis, then briefly describes several strategies for improving the catalytic performance of materials, and finally classifies and summarizes the array catalytic materials used for water electrolysis. It is expected to provide reference for the design and synthesis of electrocatalytic materials in the future.
    Hydrogen energy is considered to be one of the clean energy sources most likely to alternate fossil fuels. The exploration of catalytic materials suitable for electrocatalytic water splitting to produce hydrogen has become an important subject in the field of water electrolysis. Limited to the phenomena of easy stacking of nano-powder materials and poor conductivity during the catalytic reaction, the combination of nano-active materials and conductive substrates to construct three-dimensional (3D) array electrodes with open porous structures has become a research hotspot. This article first summarizes the advantages of 3D array electrodes for water electrolysis, then briefly describes several strategies for improving the catalytic performance of materials, and finally classifies and summarizes the array catalytic materials used for water electrolysis. It is expected to provide reference for the design and synthesis of electrocatalytic materials in the future.
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  • [1]
    Suen N T, Hung S F, Quan Q, et al. Electrocatalysis for the oxygen evolution reaction: Recent development and future perspectives. Chemical Society Reviews, 2017, 46(2): 337-365.
    [2]
    Seh Z W, Kibsgaard J, Dickens C F, et al. Combining theory and experiment in electrocatalysis: Insights into materials design. Science, 2017, 355:4998.
    [3]
    Luo M, Guo S. Strain-controlled electrocatalysis on multimetallic nanomaterials. Nature Reviews Materials, 2017, 2(11): 17059.
    [4]
    Chu S, Majumdar A. Opportunities and challenges for a sustainable energy future. Nature, 2012, 488(7411): 294-303.
    [5]
    Trasatti S. Water electrolysis: Who first? Journal of Electroanalytical Chemistry, 1999, 476(1): 90-91.
    [6]
    Levie R D. The electrolysis of water. Journal of Electroanalytical Chemistry, 1999, 476(1): 92-93.
    [7]
    Benck J D, Hellstern T R, Kibsgaard J, et al. Catalyzing the hydrogen evolution reaction (HER) with molybdenum sulfide nanomaterials. ACS Catalysis, 2014, 4(11): 3957-3971.
    [8]
    Zou X, Zhang Y. Noble metal-free hydrogen evolution catalysts for water splitting. Chemical Society Reviews, 2015, 44(15): 5148-5180.
    [9]
    Huang Z F, Song J, Pan L, et al. Tungsten oxides for photocatalysis, electrochemistry, and phototherapy. Advanced Materials, 2015, 27(36): 5309-5327.
    [10]
    Zhang X, Klaver P, Van Santen R, et al. Oxygen evolution at hematite surfaces: The impact of structure and oxygen vacancies on lowering the overpotential. The Journal of Physical Chemistry C, 2016, 120(32): 18201-18208.
    [11]
    TONG S S, WANG X J, LI Q C, et al. Progress onelectrocatalysts of hydrogen evolution reaction based on carbon fiber materials. Chinese Journal of Analytical Chemistry, 2016, 44(9): 1447-1457.
    [12]
    Cook T R, Dogutan D K, Reece S Y, et al. Solar energy supply and storage for the legacy and nonlegacy worlds . Chemical Reviews, 2010, 110(11): 6474-6502.
    [13]
    Jin H, Guo C, Liu X, et al. Emerging two-dimensional nanomaterials for electrocatalysis. Chemical Reviews, 2018, 118(13): 6337-6408.
    [14]
    Chen D, Zou Y, Wang S. Surface chemical-functionalization of ultrathin two-dimensional nanomaterials for electrocatalysis. Materials Today Energy, 2019, 12:250-268.
    [15]
    Kong X, Liu Q, Zhang C, et al. Elemental two-dimensional nanosheets beyond graphene. Chemical Society Reviews, 2017, 46(8): 2127-2157.
    [16]
    Guo X L, Zhang J M, Xu W N, et al. Growth of NiMn LDH nanosheet arrays on KCu7S4 microwires for hybrid supercapacitors with enhanced electrochemical performance. Journal of Materials Chemistry A, 2017, 5(39): 20579-20587.
    [17]
    Zhang T, Wu M Y, Yan D Y, et al. Engineering oxygen vacancy on NiO nanorod arrays for alkaline hydrogen evolution. Nano Energy, 2018, 43:103-109.
    [18]
    Wang X, Yu L, Guan B Y, et al. Metal-organic framework hybrid-assisted formation of Co3O4/Co-Fe oxide double-shelled nanoboxes for enhanced oxygen evolution. Advanced Materials, 2018, 30(29):1801211.
    [19]
    Wu Y, Meng Y, Hou J, et al. Orienting active crystal planes of new class lacunaris Fe2PO5 polyhedrons for robust water oxidation in alkaline and neutral media. Advanced Functional Materials, 2018, 28(35): 1801397.
    [20]
    Chaudhari N K, Jin H, Kim B, et al. Nanostructured materials on 3D nickel foam as electrocatalysts for water splitting. Nanoscale, 2017, 9(34): 12231-12247.
    [21]
    Liu J, Zhu D, Zheng Y, et al. Self-supported earth-abundant nanoarrays as efficient and robust electrocatalysts for energy-related reactions. ACS Catalysis, 2018, 8(7): 6707-6732.
    [22]
    Sun X, Huo J, Yang Y, et al. The Co3O4 nanosheet array as support for MoS2 as highly efficient electrocatalysts for hydrogen evolution reaction. Journal of Energy Chemistry, 2017, 26(6): 1136-1139.
    [23]
    Faber M S, Jin S. Earth-abundant inorganic electrocatalysts and their nanostructures for energy conversion applications. Energy & Environmental Science, 2014, 7(11): 3519-3542.
    [24]
    Fang M, Dong G, Wei R, et al. Hierarchical nanostructures: Design for sustainable water splitting. Advanced Energy Materials, 2017, 7(23): 1700559.
    [25]
    Jiao Y, Zheng Y, Jaroniec M, et al. Design of electrocatalysts for oxygen- and hydrogen-involving energy conversion reactions. Chemical Society Reviews, 2015, 44(8): 2060-2086.
    [26]
    Kibler L A. Hydrogen electrocatalysis. ChemPhysChem, 2006, 7(5): 985-991.
    [27]
    Li Y, Wang H, Xie L, et al. MoS2 nanoparticles grown on graphene: An advanced catalyst for the hydrogen evolution reaction. Journal of the American Chemistry Society, 2011, 133(19): 7296-7299.
    [28]
    Zhao G, Sun Y, Zhou W, et al. Superior photocatalytic H2production with cocatalytic Co/Ni species anchored on sulfide semiconductor. Advanced Materials, 2017, 29(40): 1703258.
    [29]
    Staszak-Jirkovsky J, Malliakas C D, Lopes P P, et al. Design of active and stable Co-Mo-Sx chalcogels as pH-universal catalysts for the hydrogen evolution reaction. Nature Materials, 2016, 15(2): 197-203.
    [30]
    Kim J S, Kim B, Kim H, et al. Recent progress on multimetal oxide catalysts for the oxygen evolution reaction. Advanced Energy Materials, 2018, 8(11):1702774.
    [31]
    Rossmeisl J, Logadottir A, Nørskov J K. Electrolysis of water on (oxidized) metal surfaces. Chemical Physics, 2005, 319: 178-184.
    [32]
    Man I C, Su H Y, Calle-Vallejo F, et al. Universality in oxygen evolution electrocatalysis on oxide surfaces. ChemCatChem, 2011, 3(7): 1159-1165.
    [33]
    Xu Z, Rossmeisl J, Kitchin J R. A Linear response DFT+U study of trends in the oxygen evolution activity of transition metal rutile dioxides. The Journal of Physical Chemistry C, 2015, 119(9): 4827-4833.
    [34]
    Cheng F, Su Y, Liang J, et al. MnO2-based nanostructures as catalysts for electrochemical oxygen reduction in alkaline media. Chemistry of Materials, 2010, 22(3): 898-905.
    [35]
    Ma T Y, Dai S, Jaroniec M, et al. Metal-organic framework derived hybrid Co3O4-carbon porous nanowire arrays as reversible oxygen evolution electrodes. Journal of the American Chemistry Society, 2014, 136(39): 13925-13931.
    [36]
    Li J, Yang Z, Lin Y, et al. Self-supported molybdenum doping Ni3S2 nanoneedles as efficient bifunctional catalysts for overall water splitting. New Journal of Chemistry, 2020, 44(20): 8578-8586.
    [37]
    Zhang J, Song M, Wang J, et al. In-situ transformation to accordion-like core-shell structured metal@metallic hydroxide nanosheet from nanorod morphology for overall water-splitting in alkaline media. Journal of Colloid and Interface Science, 2020, 559:105-114.
    [38]
    Aqueel Ahmed A T, Pawar S M, InamdarA I, et al. A morphologically engineered robust bifunctional CuCo2O4nanosheet catalyst for highly efficient overall water splitting. Advanced Materials Interfaces, 2019, 7(2): 1901515.
    [39]
    Guo C, Liu X, Gao L, et al. Fe-doped Ni2P nanosheets with porous structure for electroreduction of nitrogen to ammonia under ambient conditions. Applied Catalysis B: Environmental, 2020, 263:118296.
    [40]
    Niu H J, Zhang L, Feng J J, et al. Graphene-encapsulated cobalt nanoparticles embedded in porous nitrogen-doped graphitic carbon nanosheets as efficient electrocatalysts for oxygen reduction reaction. Journal of Colloid and Interface Science, 2019, 552:744-751.
    [41]
    Zhang J, Zhang M, Zeng Y, et al. Single Fe atom on hierarchically porous S, N-codoped nanocarbon derived from porphyra enable boosted oxygen catalysis for rechargeable Zn-air batteries. Small, 2019, 15(24): 1900307.
    [42]
    Zhang H, Liu Q, Xu J, et al. Holey ruthenium nanosheets with moderate aluminum modulation toward hydrogen evolution. Inorg Chem, 2019, 58(13): 8267-8270.
    [43]
    Liu Q, Wei L, Liu Q, et al. Anion engineering on 3D Ni3S2nanosheets array toward water splitting. ACS Applied Energy Materials, 2018, 1(7): 3488-3496.
    [44]
    Wu Z, Nie D, Song M, et al. Facile synthesis of Co-Fe-B-P nanochains as an efficient bifunctional electrocatalyst for overall water-splitting. Nanoscale, 2019, 11(15): 7506-7512.
    [45]
    Chen C, Yan D, Wang Y, et al. BN pairs enriched defective carbon nanosheets for ammonia synthesis with high efficiency. Small, 2019, 15(7): 1805029.
    [46]
    Liu Q, Liu Q, Kong X. Anion engineering on free-standing two-dimensional MoS2nanosheets toward hydrogen evolution. Inorganic Chemistry, 2017, 56(19): 11462-11465.
    [47]
    Duan J J, Han Z, Zhang R L, et al. Iron, manganese co-doped Ni3S2 nanoflowers in situ assembled by ultrathin nanosheets as a robust electrocatalyst for oxygen evolution reaction. Journal of Colloid and Interface Science, 2021, 588:248-256.
    [48]
    Nadeem M, Yasin G, Arif M, et al. Highly active sites of Pt/Er dispersed N-doped hierarchical porous carbon for trifunctional electrocatalyst. Chemical Engineering Journal, 2021, 409:128205.
    [49]
    Jin Q, Ren B, Cui H, et al. Nitrogen and cobalt co-doped carbon nanotube films as binder-free trifunctional electrode for flexible zinc-air battery and self-powered overall water splitting. Applied Catalysis B: Environmental, 2021, 283:119643.
    [50]
    Mohammed-Ibrahim J, Sun X. Recent progress on earth abundant electrocatalysts for hydrogen evolution reaction (HER) in alkaline medium to achieve efficient water splitting: A review. Journal of Energy Chemistry, 2019, 34:111-160.
    [51]
    Wang G, Ling Y, Wang H, et al. Hydrogen-treated WO3 nanoflakes show enhanced photostability. Energy & Environmental Science, 2012, 5(3): 6180-6187.
    [52]
    Bai S, Zhang N, Gao C, et al. Defect engineering in photocatalytic materials. Nano Energy, 2018, 53:296-336.
    [53]
    Ou G, Xu Y, Wen B, et al. Tuning defects in oxides at room temperature by lithium reduction. Nature Communication, 2018, 9(1): 1302.
    [54]
    Xu L, Jiang Q, Xiao Z, et al. Plasma-engraved Co3O4nanosheets with oxygen vacancies and high surface area for the oxygen evolution reaction. Angewandte Chemie International Edition in English, 2016, 55(17): 5277-5281.
    [55]
    Tao L, Duan X, Wang C, et al. Plasma-engineered MoS2 thin-film as an efficient electrocatalyst for hydrogen evolution reaction. Chemical Communication (Camb), 2015, 51(35): 7470-7473.
    [56]
    Li C, Ma D, Mou S, et al. Porous LaFeO3 nanofiber with oxygen vacancies as an efficient electrocatalyst for N2 conversion to NH3 under ambient conditions. Journal of Energy Chemistry, 2020, 50:402-408.
    [57]
    Tong Y, Guo H, Liu D, et al. Vacancy engineering of iron-doped W18O49 nanoreactors for low-barrier electrochemical nitrogen reduction. Angewandte Chemie International Edition in English, 2020, 59(19): 7356-7361.
    [58]
    Li Y B, Liu Y P, Wang J, et al. Plasma-engineered NiO nanosheets with enriched oxygen vacancies for enhanced electrocatalytic nitrogen fixation. Inorganic Chemistry Frontiers, 2020, 7(2): 455-463.
    [59]
    Bolar S, Shit S, Murmu N C, et al. Doping-assisted phase changing effect on MoS2 towards hydrogen evolution reaction in acidic and alkaline pH. ChemElectroChem, 2020, 7(1): 336-346.
    [60]
    Voiry D, Salehi M, Silva R, et al. Conducting MoS2 nanosheets as catalysts for hydrogen evolution reaction. Nano Letters, 2013, 13(12): 6222-6227.
    [61]
    Qu M, Jiang Y, Yang M, et al. Regulating electron density of NiFe-P nanosheets electrocatalysts by a trifle of Ru for high-efficient overall water splitting. Applied Catalysis B: Environmental, 2020, 263:118324.
    [62]
    Liang C, Zou P, Nairan A, et al. Exceptional performance of hierarchical Ni-Fe oxyhydroxide@NiFe alloy nanowire array electrocatalysts for large current density water splitting. Energy & Environmental Science, 2020, 13(1): 86-95.
    [63]
    Lin J, Wang P, Wang H, et al. Defect-rich heterogeneous MoS2/NiS2nanosheets electrocatalysts for efficient overall water splitting. Advanced Science, 2019, 6(14): 1900246.
    [64]
    Mccrory C C, Jung S, Ferrer I M, et al. Benchmarking hydrogen evolving reaction and oxygen evolving reaction electrocatalysts for solar water splitting devices. Journal of the American Chemistry Society, 2015, 137(13): 4347-4357.
    [65]
    Wang X, Zhang Y, Si H, et al. Single-atom vacancy defect to trigger high-efficiency hydrogen evolution of MoS2. Journal of the American Chemistry Society, 2020, 142(9): 4298-4308.
    [66]
    Huang Z, Chen Z, Chen Z, et al. Cobalt phosphide nanorods as an efficient electrocatalyst for the hydrogen evolution reaction. Nano Energy, 2014, 9:373-382.
    [67]
    Shi Q, Zhu C, Du D, et al. Robust noble metal-based electrocatalysts for oxygen evolution reaction. Chemical Society Reviews, 2019, 48(12): 3181-3192.
    [68]
    Kuang Y, Feng G, Li P, et al. Single-crystalline ultrathin nickel nanosheets array from in situ topotactic reduction for active and stable electrocatalysis. Angewandte Chemie International Edition in English, 2016, 55(2): 693-697.
    [69]
    Cheng C, Zheng F, Zhang C, et al. High-efficiency bifunctional electrocatalyst based on 3D freestanding Cu foam in situ armored CoNi alloy nanosheet arrays for overall water splitting. Journal of Power Sources, 2019, 427:184-193.
    [70]
    Zhang Q, Li P, Zhou D, et al. Superaerophobic ultrathin Ni-Mo alloy nanosheet array from in situ topotactic reduction for hydrogen evolution reaction. Small, 2017, 13(41): 1701648.
    [71]
    Zhou D, Li P, Xu W, et al. Recent advances in non-precious metal-based electrodes for alkaline water electrolysis. ChemNanoMat, 2020, 6(3): 336-355.
    [72]
    Hu F, Zhu S, Chen S, et al. Amorphous metallic NiFeP: A conductive bulk material achieving high activity for oxygen evolution reaction in both alkaline and acidic media. Advanced Materials, 2017, 29(32): 1606570.
    [73]
    Trotochaud L, Young S L, Ranney J K, et al. Nickel-iron oxyhydroxide oxygen-evolution electrocatalysts: The role of intentional and incidental iron incorporation. Journal of the American Chemistry Society, 2014, 136(18): 6744-6753.
    [74]
    Wang B, Tang C, Wang H F, et al. A nanosized CoNi hydroxide@hydroxysulfide core-shell heterostructure for enhanced oxygen evolution. Advanced Materials, 2019, 31(4): 1805658.
    [75]
    Gong M, Li Y G, Wang H L, et al. An advanced Ni-Fe layered double hydroxide electrocatalyst for water oxidation. Journal of the American Chemical Society, 2013, 135(23): 8452-8455.
    [76]
    Jia H, Wang Z, Zheng X, et al. Interlaced Ni-Co LDH nanosheets wrapped Co9S8 nanotube with hierarchical structure toward high performance supercapacitors. Chemical Engineering Journal, 2018, 351:348-355.
    [77]
    Yang R, Zhou Y, Xing Y, et al. Synergistic coupling of CoFe-LDH arrays with NiFe-LDH nanosheet for highly efficient overall water splitting in alkaline media. Applied Catalysis B: Environmental, 2019, 253:131-139.
    [78]
    Ang L, Zhou H, Qin X, et al. Cathodic electrochemical activation of Co3O4 nanoarrays: A smart strategy to significantly boost the hydrogen evolution activity. Chemical Communication, 2018, 54(17): 2150-2153.
    [79]
    Chen Z, Kronawitter C X, Yeh Y W, et al. Activity of pure and transition metal-modified CoOOH for the oxygen evolution reaction in an alkaline medium. Journal of Materials Chemistry A, 2017, 5(2): 842-850.
    [80]
    Li Z, Shao M, An H, et al. Fast electrosynthesis of Fe-containing layered double hydroxide arrays toward highly efficient electrocatalytic oxidation reactions. Chemical Science, 2015, 6(11): 6624-6631.
    [81]
    Liu Q, Zhang H, Xu J, et al. Facile preparation of amorphous Fe-Co-Ni hydroxide arrays: A highly efficient integrated electrode for water oxidation. Inorganic Chemistry, 2018, 57(24): 15610-15617.
    [82]
    Zhu Y P, Ma T Y, Jaroniec M, et al. Self-templating synthesis of hollow Co3O4microtube arrays for highly efficient water electrolysis. Angewandte Chemie International Edition in English, 2017, 56(5): 1324-1328.
    [83]
    Sai K N S, Tang Y, Dong L, et al. N2 plasma-activated NiO nanosheet arrays with enhanced water splitting performance. Nanotechnology, 2020, 31(45): 455709
    [84]
    Joo J, Kim T, Lee J, et al. Morphology-controlled metal sulfides and phosphides for electrochemical water splitting. Advanced Materials, 2019, 31(14): 1806682.
    [85]
    Kong Q, Wang X, Tang A, et al. Three-dimensional hierarchical MoS2 nanosheet arrays/carbon cloth as flexible electrodes for high-performance hydrogen evolution reaction. Materials Letters, 2016, 177: 139-142.
    [86]
    He W, Wang F, Jia D, et al. Al-doped nickel sulfide nanosheet arrays as highly efficient bifunctional electrocatalysts for overall water splitting. Nanoscale, 2020, 12(47): 24244-24250.
    [87]
    Gong Y, Pan H, Xu Z, et al. Crossed FeCo2S4 nanosheet arrays grown on 3D nickel foam as high-efficient electrocatalyst for overall water splitting. International Journal of Hydrogen Energy, 2018, 43(36): 17259-17264.
    [88]
    Sivanantham A, Ganesan P, Shanmugam S. Hierarchical NiCo2S4nanowire arrays supported on Ni foam: An efficient and durable bifunctional electrocatalyst for oxygen and hydrogen evolution reactions. Advanced Functional Materials, 2016, 26(26): 4661-4672.
    [89]
    Wang Z, Li J, Tian X, et al. Porous nickel-iron selenide nanosheets as highly efficient electrocatalysts for oxygen evolution reaction. ACS Applied Materials & Interfaces, 2016, 8(30): 19386-19392.
    [90]
    Yang Y, Zhang W, Xiao Y, et al. CoNiSe2 heteronanorods decorated with layered-double-hydroxides for efficient hydrogen evolution. Applied Catalysis B: Environmental, 2019, 242:132-139.
    [91]
    Wang Y, Jian C, He X, et al. Self-supported molybdenum selenide nanosheets grown on urchin-like cobalt selenide nanowires array for efficient hydrogen evolution. International Journal of Hydrogen Energy, 2020, 45(24): 13282-13289.
    [92]
    Kibsgaard J, Tsai C, Chan K, et al. Designing an improved transition metal phosphide catalyst for hydrogen evolution using experimental and theoretical trends. Energy & Environmental Science, 2015, 8(10): 3022-3029.
    [93]
    Kibsgaard J, Jaramillo T F. Molybdenum phosphosulfide: An active, acid-stable, earth-abundant catalyst for the hydrogen evolution reaction. Angewandte Chemie International Edition in English, 2014, 53(52): 14433-14437.
    [94]
    Ji L, Wang J, Teng X, et al. CoP nanoframes as bifunctional electrocatalysts for efficient overall water splitting . ACS Catalysis, 2019, 10(1): 412-419.
    [95]
    Lu Y, Hou W, Yang D, et al. CoP nanosheets in-situ grown on N-doped graphene as an efficient and stable bifunctional electrocatalyst for hydrogen and oxygen evolution reactions. Electrochimica Acta, 2019, 307:543-552.
    [96]
    Guan C, Xiao W, Wu H, et al. Hollow Mo-doped CoP nanoarrays for efficient overall water splitting. Nano Energy, 2018, 48:73-80.
    [97]
    Hou C C, Chen Q Q, Wang C J, et al. Self-supported cedarlike semimetallic Cu3P nanoarrays as a 3D high-performance Janus electrode for both oxygen and hydrogen evolution under basic conditions. ACS Applied Materials & Interfaces, 2016, 8(35): 23037-23048.
    [98]
    Pu Z, Liu Q, Asiri A M, et al. Tungsten phosphide nanorod arrays directly grown on carbon cloth: A highly efficient and stable hydrogen evolution cathode at all pH values. ACS Applied Materials & Interfaces, 2014, 6(24): 21874-21879.
    [99]
    Liang Y, Liu Q, Asiri A M, et al. Self-supported FeP nanorod arrays: A cost-effective 3D hydrogen evolution cathode with high catalytic activity. ACS Catalysis, 2014, 4(11): 4065-4069.
    [100]
    Zhu W, Tang C, Liu D, et al. A self-standing nanoporous MoP2 nanosheet array: An advanced pH-universal catalytic electrode for the hydrogen evolution reaction. Journal of Materials Chemistry A, 2016, 4(19): 7169-7173.
    [101]
    Li D, Xing Y, Yang R, et al. Holey cobalt-iron nitride nanosheet arrays as high-performance bifunctional electrocatalysts for overall water splitting. ACS Applied Materials & Interfaces, 2020, 12(26): 29253-29263.
    [102]
    Li J, Kong X, Jiang M, et al. Hierarchically structured CoN/Cu3N nanotube array supported on copper foam as an efficient bifunctional electrocatalyst for overall water splitting. Inorganic Chemistry Frontiers, 2018, 5(11): 2906-2913.
    [103]
    Lu Y, Li Z, Xu Y, et al. Bimetallic Co-Mo nitride nanosheet arrays as high-performance bifunctional electrocatalysts for overall water splitting. Chemical Engineering Journal, 2021, 411:128433.
    [104]
    Ma Y Y, Lang Z L, Yan L K, et al. Highly efficient hydrogen evolution triggered by a multi-interfacial Ni/WC hybrid electrocatalyst. Energy & Environmental Science, 2018, 11(8): 2114-2123.
    [105]
    Chen J, Ren B, Cui H, et al. Constructing pure phase tungsten-based bimetallic carbide nanosheet as an efficient bifunctional electrocatalyst for overall water splitting. Small, 2020, 16(23): 1907556.
    [106]
    Xu H, Wan J, ZhangH, et al. A new platinum-like efficient electrocatalyst for hydrogen evolution reaction at all pH: Single-crystal metallic interweaved V8C7networks. Advanced Energy Materials, 2018, 8(23): 1800575.
    [107]
    Duan J, Chen S, Zhao C. Ultrathin metal-organic framework array for efficient electrocatalytic water splitting . Nature Communication, 2017, 8:15341.
    [108]
    Zhang X X, Liu Q,Shi X F, et al. An Fe-MOF nanosheet array with superior activity towards the alkaline oxygen evolution reaction. Inorganic Chemistry Frontiers, 2018, 5(6): 1405-1408.
    [109]
    Han X, Wu X, Deng Y, et al. Ultrafine Pt nanoparticle-decorated pyrite-type CoS2nanosheet arrays coated on carbon cloth as a bifunctional electrode for overall water splitting. Advanced Energy Materials, 2018, 8(24): 1800935.
    [110]
    Wei C, Fan X, Deng X, et al. Ruthenium doped Ni2P nanosheet arrays for active hydrogen evolution in neutral and alkaline water. Sustainable Energy & Fuels, 2020, 4(4): 1883-1890.
    [111]
    Wang Y, Zheng P, Li M, et al. Interfacial synergy between dispersed Ru sub-nanoclusters and porous NiFe layered double hydroxide on accelerated overall water splitting by intermediate modulation. Nanoscale, 2020, 12: 9669-9679.
    [112]
    Zhu J, Cai L, Yin X, et al. Enhanced electrocatalytic hydrogen evolution activity in single-atom Pt-decorated VS2nanosheets. ACS Nano, 2020, 14(5):5600-5608.
    [113]
    Gou Y, Liu Q, Shi X, et al. CaMoO4 nanosheet arrays for efficient and durable water oxidation electrocatalysis under alkaline conditions. Chemical Communication, 2018, 54(40): 5066-5069.
    [114]
    Li Y, Hu L, Zheng W, et al. Ni/Co-based nanosheet arrays for efficient oxygen evolution reaction. Nano Energy, 2018, 52:360-368.
    [115]
    Xie J, Qu H, Lei F, et al. Partially amorphous nickel-iron layered double hydroxide nanosheet arrays for robust bifunctional electrocatalysis. Journal of Materials Chemistry A, 2018, 6(33): 16121-16129.
    [116]
    Xi W, Yan G, Tan H, et al. Superaerophobic P-doped Ni(OH)2/NiMoO4 hierarchical nanosheet arrays grown on Ni foam for electrocatalytic overall water splitting. Dalton Transactions, 2018, 47(26): 8787-8793.
    [117]
    Xiang K, Guo J, Xu J, et al. Surface sulfurization of NiCo-layered double hydroxide nanosheets enable superior and durable oxygen evolution electrocatalysis. ACS Applied Energy Materials, 2018, 1(8): 4040-4049.
    [118]
    Zhang J, Jiang Y, Wang Y, et al. Ultrathin carbon coated mesoporous Ni-NiFe2O4 nanosheet arrays for efficient overall water splitting. Electrochimica Acta, 2019, 321:134652.
    [119]
    Ma P, Luo S, Luo Y, et al. Vertically aligned FeOOH nanosheet arrays on alkali-treated nickel foam as highly efficient electrocatalyst for oxygen evolution reaction. Journal of Colloid and Interface Science, 2020, 574:241-250.
    [120]
    Zheng J, Chen X, Zhong X, et al. Hierarchical porous NC@CuCo nitride nanosheet networks: Highly efficient bifunctional electrocatalyst for overall water splitting and selective electrooxidation of benzyl alcohol. Advanced Functional Materials, 2017, 27(46): 1704169.
    [121]
    Wang Y, Xie C, Liu D, et al. Nanoparticle-stacked porous nickel-iron nitride nanosheet: A highly efficient bifunctional electrocatalyst for overall water splitting. ACS Applied Materials & Interfaces, 2016, 8(29):18652-18657.
    [122]
    Yuan H, Wei S, Tang B, et al. Self-supported 3D ultra-thin cobalt-nickel-boron nanoflakes as an efficient electrocatalyst for oxygen evolution reaction. ChemSusChem, 2020, 13(14):3662-3670.
    [123]
    Hou L, Shao M, Li J, et al. Two-dimensional ultrathin arrays of CoP: Electronic modulation toward high performance overall water splitting. Nano Energy, 2017, 41:583-590.
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    [1]
    Suen N T, Hung S F, Quan Q, et al. Electrocatalysis for the oxygen evolution reaction: Recent development and future perspectives. Chemical Society Reviews, 2017, 46(2): 337-365.
    [2]
    Seh Z W, Kibsgaard J, Dickens C F, et al. Combining theory and experiment in electrocatalysis: Insights into materials design. Science, 2017, 355:4998.
    [3]
    Luo M, Guo S. Strain-controlled electrocatalysis on multimetallic nanomaterials. Nature Reviews Materials, 2017, 2(11): 17059.
    [4]
    Chu S, Majumdar A. Opportunities and challenges for a sustainable energy future. Nature, 2012, 488(7411): 294-303.
    [5]
    Trasatti S. Water electrolysis: Who first? Journal of Electroanalytical Chemistry, 1999, 476(1): 90-91.
    [6]
    Levie R D. The electrolysis of water. Journal of Electroanalytical Chemistry, 1999, 476(1): 92-93.
    [7]
    Benck J D, Hellstern T R, Kibsgaard J, et al. Catalyzing the hydrogen evolution reaction (HER) with molybdenum sulfide nanomaterials. ACS Catalysis, 2014, 4(11): 3957-3971.
    [8]
    Zou X, Zhang Y. Noble metal-free hydrogen evolution catalysts for water splitting. Chemical Society Reviews, 2015, 44(15): 5148-5180.
    [9]
    Huang Z F, Song J, Pan L, et al. Tungsten oxides for photocatalysis, electrochemistry, and phototherapy. Advanced Materials, 2015, 27(36): 5309-5327.
    [10]
    Zhang X, Klaver P, Van Santen R, et al. Oxygen evolution at hematite surfaces: The impact of structure and oxygen vacancies on lowering the overpotential. The Journal of Physical Chemistry C, 2016, 120(32): 18201-18208.
    [11]
    TONG S S, WANG X J, LI Q C, et al. Progress onelectrocatalysts of hydrogen evolution reaction based on carbon fiber materials. Chinese Journal of Analytical Chemistry, 2016, 44(9): 1447-1457.
    [12]
    Cook T R, Dogutan D K, Reece S Y, et al. Solar energy supply and storage for the legacy and nonlegacy worlds . Chemical Reviews, 2010, 110(11): 6474-6502.
    [13]
    Jin H, Guo C, Liu X, et al. Emerging two-dimensional nanomaterials for electrocatalysis. Chemical Reviews, 2018, 118(13): 6337-6408.
    [14]
    Chen D, Zou Y, Wang S. Surface chemical-functionalization of ultrathin two-dimensional nanomaterials for electrocatalysis. Materials Today Energy, 2019, 12:250-268.
    [15]
    Kong X, Liu Q, Zhang C, et al. Elemental two-dimensional nanosheets beyond graphene. Chemical Society Reviews, 2017, 46(8): 2127-2157.
    [16]
    Guo X L, Zhang J M, Xu W N, et al. Growth of NiMn LDH nanosheet arrays on KCu7S4 microwires for hybrid supercapacitors with enhanced electrochemical performance. Journal of Materials Chemistry A, 2017, 5(39): 20579-20587.
    [17]
    Zhang T, Wu M Y, Yan D Y, et al. Engineering oxygen vacancy on NiO nanorod arrays for alkaline hydrogen evolution. Nano Energy, 2018, 43:103-109.
    [18]
    Wang X, Yu L, Guan B Y, et al. Metal-organic framework hybrid-assisted formation of Co3O4/Co-Fe oxide double-shelled nanoboxes for enhanced oxygen evolution. Advanced Materials, 2018, 30(29):1801211.
    [19]
    Wu Y, Meng Y, Hou J, et al. Orienting active crystal planes of new class lacunaris Fe2PO5 polyhedrons for robust water oxidation in alkaline and neutral media. Advanced Functional Materials, 2018, 28(35): 1801397.
    [20]
    Chaudhari N K, Jin H, Kim B, et al. Nanostructured materials on 3D nickel foam as electrocatalysts for water splitting. Nanoscale, 2017, 9(34): 12231-12247.
    [21]
    Liu J, Zhu D, Zheng Y, et al. Self-supported earth-abundant nanoarrays as efficient and robust electrocatalysts for energy-related reactions. ACS Catalysis, 2018, 8(7): 6707-6732.
    [22]
    Sun X, Huo J, Yang Y, et al. The Co3O4 nanosheet array as support for MoS2 as highly efficient electrocatalysts for hydrogen evolution reaction. Journal of Energy Chemistry, 2017, 26(6): 1136-1139.
    [23]
    Faber M S, Jin S. Earth-abundant inorganic electrocatalysts and their nanostructures for energy conversion applications. Energy & Environmental Science, 2014, 7(11): 3519-3542.
    [24]
    Fang M, Dong G, Wei R, et al. Hierarchical nanostructures: Design for sustainable water splitting. Advanced Energy Materials, 2017, 7(23): 1700559.
    [25]
    Jiao Y, Zheng Y, Jaroniec M, et al. Design of electrocatalysts for oxygen- and hydrogen-involving energy conversion reactions. Chemical Society Reviews, 2015, 44(8): 2060-2086.
    [26]
    Kibler L A. Hydrogen electrocatalysis. ChemPhysChem, 2006, 7(5): 985-991.
    [27]
    Li Y, Wang H, Xie L, et al. MoS2 nanoparticles grown on graphene: An advanced catalyst for the hydrogen evolution reaction. Journal of the American Chemistry Society, 2011, 133(19): 7296-7299.
    [28]
    Zhao G, Sun Y, Zhou W, et al. Superior photocatalytic H2production with cocatalytic Co/Ni species anchored on sulfide semiconductor. Advanced Materials, 2017, 29(40): 1703258.
    [29]
    Staszak-Jirkovsky J, Malliakas C D, Lopes P P, et al. Design of active and stable Co-Mo-Sx chalcogels as pH-universal catalysts for the hydrogen evolution reaction. Nature Materials, 2016, 15(2): 197-203.
    [30]
    Kim J S, Kim B, Kim H, et al. Recent progress on multimetal oxide catalysts for the oxygen evolution reaction. Advanced Energy Materials, 2018, 8(11):1702774.
    [31]
    Rossmeisl J, Logadottir A, Nørskov J K. Electrolysis of water on (oxidized) metal surfaces. Chemical Physics, 2005, 319: 178-184.
    [32]
    Man I C, Su H Y, Calle-Vallejo F, et al. Universality in oxygen evolution electrocatalysis on oxide surfaces. ChemCatChem, 2011, 3(7): 1159-1165.
    [33]
    Xu Z, Rossmeisl J, Kitchin J R. A Linear response DFT+U study of trends in the oxygen evolution activity of transition metal rutile dioxides. The Journal of Physical Chemistry C, 2015, 119(9): 4827-4833.
    [34]
    Cheng F, Su Y, Liang J, et al. MnO2-based nanostructures as catalysts for electrochemical oxygen reduction in alkaline media. Chemistry of Materials, 2010, 22(3): 898-905.
    [35]
    Ma T Y, Dai S, Jaroniec M, et al. Metal-organic framework derived hybrid Co3O4-carbon porous nanowire arrays as reversible oxygen evolution electrodes. Journal of the American Chemistry Society, 2014, 136(39): 13925-13931.
    [36]
    Li J, Yang Z, Lin Y, et al. Self-supported molybdenum doping Ni3S2 nanoneedles as efficient bifunctional catalysts for overall water splitting. New Journal of Chemistry, 2020, 44(20): 8578-8586.
    [37]
    Zhang J, Song M, Wang J, et al. In-situ transformation to accordion-like core-shell structured metal@metallic hydroxide nanosheet from nanorod morphology for overall water-splitting in alkaline media. Journal of Colloid and Interface Science, 2020, 559:105-114.
    [38]
    Aqueel Ahmed A T, Pawar S M, InamdarA I, et al. A morphologically engineered robust bifunctional CuCo2O4nanosheet catalyst for highly efficient overall water splitting. Advanced Materials Interfaces, 2019, 7(2): 1901515.
    [39]
    Guo C, Liu X, Gao L, et al. Fe-doped Ni2P nanosheets with porous structure for electroreduction of nitrogen to ammonia under ambient conditions. Applied Catalysis B: Environmental, 2020, 263:118296.
    [40]
    Niu H J, Zhang L, Feng J J, et al. Graphene-encapsulated cobalt nanoparticles embedded in porous nitrogen-doped graphitic carbon nanosheets as efficient electrocatalysts for oxygen reduction reaction. Journal of Colloid and Interface Science, 2019, 552:744-751.
    [41]
    Zhang J, Zhang M, Zeng Y, et al. Single Fe atom on hierarchically porous S, N-codoped nanocarbon derived from porphyra enable boosted oxygen catalysis for rechargeable Zn-air batteries. Small, 2019, 15(24): 1900307.
    [42]
    Zhang H, Liu Q, Xu J, et al. Holey ruthenium nanosheets with moderate aluminum modulation toward hydrogen evolution. Inorg Chem, 2019, 58(13): 8267-8270.
    [43]
    Liu Q, Wei L, Liu Q, et al. Anion engineering on 3D Ni3S2nanosheets array toward water splitting. ACS Applied Energy Materials, 2018, 1(7): 3488-3496.
    [44]
    Wu Z, Nie D, Song M, et al. Facile synthesis of Co-Fe-B-P nanochains as an efficient bifunctional electrocatalyst for overall water-splitting. Nanoscale, 2019, 11(15): 7506-7512.
    [45]
    Chen C, Yan D, Wang Y, et al. BN pairs enriched defective carbon nanosheets for ammonia synthesis with high efficiency. Small, 2019, 15(7): 1805029.
    [46]
    Liu Q, Liu Q, Kong X. Anion engineering on free-standing two-dimensional MoS2nanosheets toward hydrogen evolution. Inorganic Chemistry, 2017, 56(19): 11462-11465.
    [47]
    Duan J J, Han Z, Zhang R L, et al. Iron, manganese co-doped Ni3S2 nanoflowers in situ assembled by ultrathin nanosheets as a robust electrocatalyst for oxygen evolution reaction. Journal of Colloid and Interface Science, 2021, 588:248-256.
    [48]
    Nadeem M, Yasin G, Arif M, et al. Highly active sites of Pt/Er dispersed N-doped hierarchical porous carbon for trifunctional electrocatalyst. Chemical Engineering Journal, 2021, 409:128205.
    [49]
    Jin Q, Ren B, Cui H, et al. Nitrogen and cobalt co-doped carbon nanotube films as binder-free trifunctional electrode for flexible zinc-air battery and self-powered overall water splitting. Applied Catalysis B: Environmental, 2021, 283:119643.
    [50]
    Mohammed-Ibrahim J, Sun X. Recent progress on earth abundant electrocatalysts for hydrogen evolution reaction (HER) in alkaline medium to achieve efficient water splitting: A review. Journal of Energy Chemistry, 2019, 34:111-160.
    [51]
    Wang G, Ling Y, Wang H, et al. Hydrogen-treated WO3 nanoflakes show enhanced photostability. Energy & Environmental Science, 2012, 5(3): 6180-6187.
    [52]
    Bai S, Zhang N, Gao C, et al. Defect engineering in photocatalytic materials. Nano Energy, 2018, 53:296-336.
    [53]
    Ou G, Xu Y, Wen B, et al. Tuning defects in oxides at room temperature by lithium reduction. Nature Communication, 2018, 9(1): 1302.
    [54]
    Xu L, Jiang Q, Xiao Z, et al. Plasma-engraved Co3O4nanosheets with oxygen vacancies and high surface area for the oxygen evolution reaction. Angewandte Chemie International Edition in English, 2016, 55(17): 5277-5281.
    [55]
    Tao L, Duan X, Wang C, et al. Plasma-engineered MoS2 thin-film as an efficient electrocatalyst for hydrogen evolution reaction. Chemical Communication (Camb), 2015, 51(35): 7470-7473.
    [56]
    Li C, Ma D, Mou S, et al. Porous LaFeO3 nanofiber with oxygen vacancies as an efficient electrocatalyst for N2 conversion to NH3 under ambient conditions. Journal of Energy Chemistry, 2020, 50:402-408.
    [57]
    Tong Y, Guo H, Liu D, et al. Vacancy engineering of iron-doped W18O49 nanoreactors for low-barrier electrochemical nitrogen reduction. Angewandte Chemie International Edition in English, 2020, 59(19): 7356-7361.
    [58]
    Li Y B, Liu Y P, Wang J, et al. Plasma-engineered NiO nanosheets with enriched oxygen vacancies for enhanced electrocatalytic nitrogen fixation. Inorganic Chemistry Frontiers, 2020, 7(2): 455-463.
    [59]
    Bolar S, Shit S, Murmu N C, et al. Doping-assisted phase changing effect on MoS2 towards hydrogen evolution reaction in acidic and alkaline pH. ChemElectroChem, 2020, 7(1): 336-346.
    [60]
    Voiry D, Salehi M, Silva R, et al. Conducting MoS2 nanosheets as catalysts for hydrogen evolution reaction. Nano Letters, 2013, 13(12): 6222-6227.
    [61]
    Qu M, Jiang Y, Yang M, et al. Regulating electron density of NiFe-P nanosheets electrocatalysts by a trifle of Ru for high-efficient overall water splitting. Applied Catalysis B: Environmental, 2020, 263:118324.
    [62]
    Liang C, Zou P, Nairan A, et al. Exceptional performance of hierarchical Ni-Fe oxyhydroxide@NiFe alloy nanowire array electrocatalysts for large current density water splitting. Energy & Environmental Science, 2020, 13(1): 86-95.
    [63]
    Lin J, Wang P, Wang H, et al. Defect-rich heterogeneous MoS2/NiS2nanosheets electrocatalysts for efficient overall water splitting. Advanced Science, 2019, 6(14): 1900246.
    [64]
    Mccrory C C, Jung S, Ferrer I M, et al. Benchmarking hydrogen evolving reaction and oxygen evolving reaction electrocatalysts for solar water splitting devices. Journal of the American Chemistry Society, 2015, 137(13): 4347-4357.
    [65]
    Wang X, Zhang Y, Si H, et al. Single-atom vacancy defect to trigger high-efficiency hydrogen evolution of MoS2. Journal of the American Chemistry Society, 2020, 142(9): 4298-4308.
    [66]
    Huang Z, Chen Z, Chen Z, et al. Cobalt phosphide nanorods as an efficient electrocatalyst for the hydrogen evolution reaction. Nano Energy, 2014, 9:373-382.
    [67]
    Shi Q, Zhu C, Du D, et al. Robust noble metal-based electrocatalysts for oxygen evolution reaction. Chemical Society Reviews, 2019, 48(12): 3181-3192.
    [68]
    Kuang Y, Feng G, Li P, et al. Single-crystalline ultrathin nickel nanosheets array from in situ topotactic reduction for active and stable electrocatalysis. Angewandte Chemie International Edition in English, 2016, 55(2): 693-697.
    [69]
    Cheng C, Zheng F, Zhang C, et al. High-efficiency bifunctional electrocatalyst based on 3D freestanding Cu foam in situ armored CoNi alloy nanosheet arrays for overall water splitting. Journal of Power Sources, 2019, 427:184-193.
    [70]
    Zhang Q, Li P, Zhou D, et al. Superaerophobic ultrathin Ni-Mo alloy nanosheet array from in situ topotactic reduction for hydrogen evolution reaction. Small, 2017, 13(41): 1701648.
    [71]
    Zhou D, Li P, Xu W, et al. Recent advances in non-precious metal-based electrodes for alkaline water electrolysis. ChemNanoMat, 2020, 6(3): 336-355.
    [72]
    Hu F, Zhu S, Chen S, et al. Amorphous metallic NiFeP: A conductive bulk material achieving high activity for oxygen evolution reaction in both alkaline and acidic media. Advanced Materials, 2017, 29(32): 1606570.
    [73]
    Trotochaud L, Young S L, Ranney J K, et al. Nickel-iron oxyhydroxide oxygen-evolution electrocatalysts: The role of intentional and incidental iron incorporation. Journal of the American Chemistry Society, 2014, 136(18): 6744-6753.
    [74]
    Wang B, Tang C, Wang H F, et al. A nanosized CoNi hydroxide@hydroxysulfide core-shell heterostructure for enhanced oxygen evolution. Advanced Materials, 2019, 31(4): 1805658.
    [75]
    Gong M, Li Y G, Wang H L, et al. An advanced Ni-Fe layered double hydroxide electrocatalyst for water oxidation. Journal of the American Chemical Society, 2013, 135(23): 8452-8455.
    [76]
    Jia H, Wang Z, Zheng X, et al. Interlaced Ni-Co LDH nanosheets wrapped Co9S8 nanotube with hierarchical structure toward high performance supercapacitors. Chemical Engineering Journal, 2018, 351:348-355.
    [77]
    Yang R, Zhou Y, Xing Y, et al. Synergistic coupling of CoFe-LDH arrays with NiFe-LDH nanosheet for highly efficient overall water splitting in alkaline media. Applied Catalysis B: Environmental, 2019, 253:131-139.
    [78]
    Ang L, Zhou H, Qin X, et al. Cathodic electrochemical activation of Co3O4 nanoarrays: A smart strategy to significantly boost the hydrogen evolution activity. Chemical Communication, 2018, 54(17): 2150-2153.
    [79]
    Chen Z, Kronawitter C X, Yeh Y W, et al. Activity of pure and transition metal-modified CoOOH for the oxygen evolution reaction in an alkaline medium. Journal of Materials Chemistry A, 2017, 5(2): 842-850.
    [80]
    Li Z, Shao M, An H, et al. Fast electrosynthesis of Fe-containing layered double hydroxide arrays toward highly efficient electrocatalytic oxidation reactions. Chemical Science, 2015, 6(11): 6624-6631.
    [81]
    Liu Q, Zhang H, Xu J, et al. Facile preparation of amorphous Fe-Co-Ni hydroxide arrays: A highly efficient integrated electrode for water oxidation. Inorganic Chemistry, 2018, 57(24): 15610-15617.
    [82]
    Zhu Y P, Ma T Y, Jaroniec M, et al. Self-templating synthesis of hollow Co3O4microtube arrays for highly efficient water electrolysis. Angewandte Chemie International Edition in English, 2017, 56(5): 1324-1328.
    [83]
    Sai K N S, Tang Y, Dong L, et al. N2 plasma-activated NiO nanosheet arrays with enhanced water splitting performance. Nanotechnology, 2020, 31(45): 455709
    [84]
    Joo J, Kim T, Lee J, et al. Morphology-controlled metal sulfides and phosphides for electrochemical water splitting. Advanced Materials, 2019, 31(14): 1806682.
    [85]
    Kong Q, Wang X, Tang A, et al. Three-dimensional hierarchical MoS2 nanosheet arrays/carbon cloth as flexible electrodes for high-performance hydrogen evolution reaction. Materials Letters, 2016, 177: 139-142.
    [86]
    He W, Wang F, Jia D, et al. Al-doped nickel sulfide nanosheet arrays as highly efficient bifunctional electrocatalysts for overall water splitting. Nanoscale, 2020, 12(47): 24244-24250.
    [87]
    Gong Y, Pan H, Xu Z, et al. Crossed FeCo2S4 nanosheet arrays grown on 3D nickel foam as high-efficient electrocatalyst for overall water splitting. International Journal of Hydrogen Energy, 2018, 43(36): 17259-17264.
    [88]
    Sivanantham A, Ganesan P, Shanmugam S. Hierarchical NiCo2S4nanowire arrays supported on Ni foam: An efficient and durable bifunctional electrocatalyst for oxygen and hydrogen evolution reactions. Advanced Functional Materials, 2016, 26(26): 4661-4672.
    [89]
    Wang Z, Li J, Tian X, et al. Porous nickel-iron selenide nanosheets as highly efficient electrocatalysts for oxygen evolution reaction. ACS Applied Materials & Interfaces, 2016, 8(30): 19386-19392.
    [90]
    Yang Y, Zhang W, Xiao Y, et al. CoNiSe2 heteronanorods decorated with layered-double-hydroxides for efficient hydrogen evolution. Applied Catalysis B: Environmental, 2019, 242:132-139.
    [91]
    Wang Y, Jian C, He X, et al. Self-supported molybdenum selenide nanosheets grown on urchin-like cobalt selenide nanowires array for efficient hydrogen evolution. International Journal of Hydrogen Energy, 2020, 45(24): 13282-13289.
    [92]
    Kibsgaard J, Tsai C, Chan K, et al. Designing an improved transition metal phosphide catalyst for hydrogen evolution using experimental and theoretical trends. Energy & Environmental Science, 2015, 8(10): 3022-3029.
    [93]
    Kibsgaard J, Jaramillo T F. Molybdenum phosphosulfide: An active, acid-stable, earth-abundant catalyst for the hydrogen evolution reaction. Angewandte Chemie International Edition in English, 2014, 53(52): 14433-14437.
    [94]
    Ji L, Wang J, Teng X, et al. CoP nanoframes as bifunctional electrocatalysts for efficient overall water splitting . ACS Catalysis, 2019, 10(1): 412-419.
    [95]
    Lu Y, Hou W, Yang D, et al. CoP nanosheets in-situ grown on N-doped graphene as an efficient and stable bifunctional electrocatalyst for hydrogen and oxygen evolution reactions. Electrochimica Acta, 2019, 307:543-552.
    [96]
    Guan C, Xiao W, Wu H, et al. Hollow Mo-doped CoP nanoarrays for efficient overall water splitting. Nano Energy, 2018, 48:73-80.
    [97]
    Hou C C, Chen Q Q, Wang C J, et al. Self-supported cedarlike semimetallic Cu3P nanoarrays as a 3D high-performance Janus electrode for both oxygen and hydrogen evolution under basic conditions. ACS Applied Materials & Interfaces, 2016, 8(35): 23037-23048.
    [98]
    Pu Z, Liu Q, Asiri A M, et al. Tungsten phosphide nanorod arrays directly grown on carbon cloth: A highly efficient and stable hydrogen evolution cathode at all pH values. ACS Applied Materials & Interfaces, 2014, 6(24): 21874-21879.
    [99]
    Liang Y, Liu Q, Asiri A M, et al. Self-supported FeP nanorod arrays: A cost-effective 3D hydrogen evolution cathode with high catalytic activity. ACS Catalysis, 2014, 4(11): 4065-4069.
    [100]
    Zhu W, Tang C, Liu D, et al. A self-standing nanoporous MoP2 nanosheet array: An advanced pH-universal catalytic electrode for the hydrogen evolution reaction. Journal of Materials Chemistry A, 2016, 4(19): 7169-7173.
    [101]
    Li D, Xing Y, Yang R, et al. Holey cobalt-iron nitride nanosheet arrays as high-performance bifunctional electrocatalysts for overall water splitting. ACS Applied Materials & Interfaces, 2020, 12(26): 29253-29263.
    [102]
    Li J, Kong X, Jiang M, et al. Hierarchically structured CoN/Cu3N nanotube array supported on copper foam as an efficient bifunctional electrocatalyst for overall water splitting. Inorganic Chemistry Frontiers, 2018, 5(11): 2906-2913.
    [103]
    Lu Y, Li Z, Xu Y, et al. Bimetallic Co-Mo nitride nanosheet arrays as high-performance bifunctional electrocatalysts for overall water splitting. Chemical Engineering Journal, 2021, 411:128433.
    [104]
    Ma Y Y, Lang Z L, Yan L K, et al. Highly efficient hydrogen evolution triggered by a multi-interfacial Ni/WC hybrid electrocatalyst. Energy & Environmental Science, 2018, 11(8): 2114-2123.
    [105]
    Chen J, Ren B, Cui H, et al. Constructing pure phase tungsten-based bimetallic carbide nanosheet as an efficient bifunctional electrocatalyst for overall water splitting. Small, 2020, 16(23): 1907556.
    [106]
    Xu H, Wan J, ZhangH, et al. A new platinum-like efficient electrocatalyst for hydrogen evolution reaction at all pH: Single-crystal metallic interweaved V8C7networks. Advanced Energy Materials, 2018, 8(23): 1800575.
    [107]
    Duan J, Chen S, Zhao C. Ultrathin metal-organic framework array for efficient electrocatalytic water splitting . Nature Communication, 2017, 8:15341.
    [108]
    Zhang X X, Liu Q,Shi X F, et al. An Fe-MOF nanosheet array with superior activity towards the alkaline oxygen evolution reaction. Inorganic Chemistry Frontiers, 2018, 5(6): 1405-1408.
    [109]
    Han X, Wu X, Deng Y, et al. Ultrafine Pt nanoparticle-decorated pyrite-type CoS2nanosheet arrays coated on carbon cloth as a bifunctional electrode for overall water splitting. Advanced Energy Materials, 2018, 8(24): 1800935.
    [110]
    Wei C, Fan X, Deng X, et al. Ruthenium doped Ni2P nanosheet arrays for active hydrogen evolution in neutral and alkaline water. Sustainable Energy & Fuels, 2020, 4(4): 1883-1890.
    [111]
    Wang Y, Zheng P, Li M, et al. Interfacial synergy between dispersed Ru sub-nanoclusters and porous NiFe layered double hydroxide on accelerated overall water splitting by intermediate modulation. Nanoscale, 2020, 12: 9669-9679.
    [112]
    Zhu J, Cai L, Yin X, et al. Enhanced electrocatalytic hydrogen evolution activity in single-atom Pt-decorated VS2nanosheets. ACS Nano, 2020, 14(5):5600-5608.
    [113]
    Gou Y, Liu Q, Shi X, et al. CaMoO4 nanosheet arrays for efficient and durable water oxidation electrocatalysis under alkaline conditions. Chemical Communication, 2018, 54(40): 5066-5069.
    [114]
    Li Y, Hu L, Zheng W, et al. Ni/Co-based nanosheet arrays for efficient oxygen evolution reaction. Nano Energy, 2018, 52:360-368.
    [115]
    Xie J, Qu H, Lei F, et al. Partially amorphous nickel-iron layered double hydroxide nanosheet arrays for robust bifunctional electrocatalysis. Journal of Materials Chemistry A, 2018, 6(33): 16121-16129.
    [116]
    Xi W, Yan G, Tan H, et al. Superaerophobic P-doped Ni(OH)2/NiMoO4 hierarchical nanosheet arrays grown on Ni foam for electrocatalytic overall water splitting. Dalton Transactions, 2018, 47(26): 8787-8793.
    [117]
    Xiang K, Guo J, Xu J, et al. Surface sulfurization of NiCo-layered double hydroxide nanosheets enable superior and durable oxygen evolution electrocatalysis. ACS Applied Energy Materials, 2018, 1(8): 4040-4049.
    [118]
    Zhang J, Jiang Y, Wang Y, et al. Ultrathin carbon coated mesoporous Ni-NiFe2O4 nanosheet arrays for efficient overall water splitting. Electrochimica Acta, 2019, 321:134652.
    [119]
    Ma P, Luo S, Luo Y, et al. Vertically aligned FeOOH nanosheet arrays on alkali-treated nickel foam as highly efficient electrocatalyst for oxygen evolution reaction. Journal of Colloid and Interface Science, 2020, 574:241-250.
    [120]
    Zheng J, Chen X, Zhong X, et al. Hierarchical porous NC@CuCo nitride nanosheet networks: Highly efficient bifunctional electrocatalyst for overall water splitting and selective electrooxidation of benzyl alcohol. Advanced Functional Materials, 2017, 27(46): 1704169.
    [121]
    Wang Y, Xie C, Liu D, et al. Nanoparticle-stacked porous nickel-iron nitride nanosheet: A highly efficient bifunctional electrocatalyst for overall water splitting. ACS Applied Materials & Interfaces, 2016, 8(29):18652-18657.
    [122]
    Yuan H, Wei S, Tang B, et al. Self-supported 3D ultra-thin cobalt-nickel-boron nanoflakes as an efficient electrocatalyst for oxygen evolution reaction. ChemSusChem, 2020, 13(14):3662-3670.
    [123]
    Hou L, Shao M, Li J, et al. Two-dimensional ultrathin arrays of CoP: Electronic modulation toward high performance overall water splitting. Nano Energy, 2017, 41:583-590.

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