ISSN 0253-2778

CN 34-1054/N

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Open AccessOpen Access JUSTC Original Paper

Construction of a colorimetric nanosensor for detecting As(III) in water

  • 1.

    Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, China

  • 2.

    Department of Chemistry, University of Science and Technology of China, Hefei 230026, China

Cite this:
https://doi.org/10.3969/j.issn.0253-2778.2020.07.001
  • Received Date: 12 April 2020
  • Accepted Date: 30 May 2020
  • Rev Recd Date: 30 May 2020
  • Publish Date: 31 July 2020
    Abstract

  • Abstract

    For the shortcomings of traditional large-scale instruments in the aspect of real time in SITU detection and operability for detecting pollutant in water. A portable colorimetric nanosensor was constructed for the real time and in situ detection of As(III) in water. The nanosensor consisted of gold nanoparticles modified with trithiocyanuric acid (TMT-AuNPs), and its detection limit for As(III) reached 0.87 μg/L. It is believed that the colorimetric nanosensor will have wide application prospects in outdoor visual detection scenarios.

    Abstract

    For the shortcomings of traditional large-scale instruments in the aspect of real time in SITU detection and operability for detecting pollutant in water. A portable colorimetric nanosensor was constructed for the real time and in situ detection of As(III) in water. The nanosensor consisted of gold nanoparticles modified with trithiocyanuric acid (TMT-AuNPs), and its detection limit for As(III) reached 0.87 μg/L. It is believed that the colorimetric nanosensor will have wide application prospects in outdoor visual detection scenarios.
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    • References(27)
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    KUNDU S, GHOSH S K, MANDAL M, et al. Functionalized silver nanoparticles as an effective medium towards trace determination of arsenic (III) in aqueous solution[J]. Talanta, 2002, 58: 935-942.
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    PILLAI A, SUNITA G, GUPTA V K, et al. A new system for the spectrphotometric determination of arsenic in environmental and biological systems [J]. Analytica Chimica Acta, 2000, 408: 111-115.
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    MAO K, ZHANG H, WANG Z, et al. Nanomaterial-based aptamer sensors for arsenic detection [J]. Biosensors and Bioelectronics, 2020, 148: 111785.
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    WILLETS K A, DUYNE R V. Localized surface plasmon resonance spectroscopy and sensing [J]. Annual Review of Physical Chemistry, 2007, 58: 267-297.
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    WU Z J, ZHAO H, XUE Y, et al. Colorimetric detection of melamine during the formation of gold nanoparticles[J]. Biosensors & Bioelectronics, 2011, 26: 2574-2578.
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    LIN Y H, CHEN C E, WANG C Y, et al. Silver nanoprobe for sensitive and selective colorimetric detection of dopamine via robust Ag-catechol interaction [J]. Chemical Communications, 2011, 47: 1181-1183.
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    YOGARAJAH N, TSAI S S H. Detection of trace arsenic in drinking water: Challenges and opportunities for microfluidics [J]. Environmental Science-Water Research & Technology, 2015, 1: 426-447.
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    GRABAR K C, FREEMAN R G, HOMMER M B, et al. Preparation and characterization of Au colloid monolayers[J]. Analytical Chemistry, 1995, 67: 735-743.
    [23]
    CHEN Y, CHEN Z P, LONG S Y, et al. Generalized ratiometric indictor based surface-enhanced raman spectroscopy for the detection of Cd2+ in environmental water samples [J]. Analytical Chemistry, 2014, 86: 12236-12242.
    [24]
    KALLURI J R, ARBNESHI T, AFRINKHAN S, et al. Use of gold nanoparticles in a simple colorimetric and ultrasensitive dynamic light scattering assay: Selective detection of arsenic in groundwater [J]. Angewandte Chemie International Edition, 2009, 48: 9668-9671.
    [25]
    BANERJEE S, KUMAR N P, SRINIVAS A, et al. Core-shell Fe3O4@Au nanocomposite as dual-functional optical probe and potential removal system for arsenic (III) from water[J]. Journal of Hazardous Materials, 2019, 375: 216-223.
    [26]
    CHANDRA V, PARK J, CHUN Y, et al. Water-dispersible magnetite-reduced graphene oxide composites for arsenic removal [J]. ACS Nano, 2010, 4(7): 3979-3986.
    [27]
    BORUAH B S, BISWAS R. Selective detection of arsenic(III) based on colorimetric approach in aqueous medium using functionalized gold nanoparticles unit[J]. Materials Research Express, 2018，5： 015059.)
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    [1]
    赵金辉, 甄国新, 刘非, 等．饮水砷暴露与肺癌发病关系的Meta分析[J]. 环境与健康杂志, 2014, 31(4) : 319-322.
    [2]
    KIRK N D. Public health - worldwide occurrences of arsenic in ground water [J]. Science, 2002, 296 (5576): 2143-2145.
    [3]
    ENSAFI A, RING A, FRITSCH I. Highly sensitive voltammetric speciation and determination of inorganic arsenic in water and alloy samples using ammonium 2-amino-1-cyclopentene-1-dithiocarboxylate [J]. Electroanalysis, 2010, 22 (11):1175-1185.
    [4]
    MORIARTY M M, KOCH I, GORDON R A, et al. Arsenic transformation mediated by gut microbiota affects the fecundity of caenorhabditis elegans [J]. Environmental Science and Technology, 2009, 43: 4818-4823.
    [5]
    CULLEN W R, REIMER K J. Arsenic speciation in the environment [J]. Chemical Reviews, 1989, 89: 713-764.
    [6]
    TOKARE J, DIWAN S A, WAALKES M P, et al. Arsenic exposure transforms human epithelial stem/progenitor cells into a cancer stem-like phenotype[J]. Environmental Health Perspectives, 2010, 118: 108-115.
    [7]
    HSIEH C J, YEN C H, KUO M S, et al. Determination of trace amounts of arsenic(III) and arsenic(V) in drinking water and arsenic(III) vapor in air by graphite-furnace atomic absorption spectrophotometry using 2,3-dimercaptopropane-1-sulfonate as a complexing agent[J]. Analytical Sciences, 1999, 15: 669-673.
    [8]
    HYMER C B, CARUSO J A. Arsenic and its speciation analysis using high-performance liquid chromatography and inductively coupled plasma mass spectrometry [J]. Journal of Chromatography A, 2004, 1045: 1-13.
    [9]
    AL-ASSAF K H, TYSON J F, UDEN P C, et al. Determination of four arsenic species in soil by sequential extraction and high performance liquid chromatography with post-column hydride generation and inductively coupled plasma optical emission spectrometry detection[J]. Journal of Analytical Atomic Spectrometry, 2009, 24: 376-384.
    [10]
    RAO C S S, RAJAN S C S, RAO N V, et al. Spectrophotometric determination of arsenic by molybdenum blue method in zinc-lead concentrates and related smelter products after chloroform extraction of iodide complex [J]. Talanta, 1993, 40: 653-656.
    [11]
    STRATTON G, WHITEHEAD H C. Colorimetric determination of arsenic in water with silver diethyldithiocarbamate [J]. Journal American Water Works Association, 1962, 54: 861-864.
    [12]
    KUNDU S, GHOSH S K, MANDAL M, et al. Functionalized silver nanoparticles as an effective medium towards trace determination of arsenic (III) in aqueous solution[J]. Talanta, 2002, 58: 935-942.
    [13]
    PILLAI A, SUNITA G, GUPTA V K, et al. A new system for the spectrphotometric determination of arsenic in environmental and biological systems [J]. Analytica Chimica Acta, 2000, 408: 111-115.
    [14]
    MAO K, ZHANG H, WANG Z, et al. Nanomaterial-based aptamer sensors for arsenic detection [J]. Biosensors and Bioelectronics, 2020, 148: 111785.
    [15]
    WILLETS K A, DUYNE R V. Localized surface plasmon resonance spectroscopy and sensing [J]. Annual Review of Physical Chemistry, 2007, 58: 267-297.
    [16]
    MOTL N E, SMITH A F, DESANTIS C J, et al. Engineering plasmonic metal colloids through composition and structural design[J]. Chemical Society Reviews, 2014, 43: 3823-3834.
    [17]
    GHOSH S K, NATH S, KUNDU S, et al. Solvent and ligand effects on the localized surface plasmon resonance (LSPR) of gold colloids [J]. Journal of Physical Chemistry B, 2004, 108: 13963-13971.
    [18]
    WU Z J, ZHAO H, XUE Y, et al. Colorimetric detection of melamine during the formation of gold nanoparticles[J]. Biosensors & Bioelectronics, 2011, 26: 2574-2578.
    [19]
    LEE J S, ULMANN P A, HAN M S, et al. “Turn-on” fluorescence probe integrated polymer nanoparticles for sensing biological thiol molecules[J]. Nano Letters, 2008, 8: 529-533.
    [20]
    LIN Y H, CHEN C E, WANG C Y, et al. Silver nanoprobe for sensitive and selective colorimetric detection of dopamine via robust Ag-catechol interaction [J]. Chemical Communications, 2011, 47: 1181-1183.
    [21]
    YOGARAJAH N, TSAI S S H. Detection of trace arsenic in drinking water: Challenges and opportunities for microfluidics [J]. Environmental Science-Water Research & Technology, 2015, 1: 426-447.
    [22]
    GRABAR K C, FREEMAN R G, HOMMER M B, et al. Preparation and characterization of Au colloid monolayers[J]. Analytical Chemistry, 1995, 67: 735-743.
    [23]
    CHEN Y, CHEN Z P, LONG S Y, et al. Generalized ratiometric indictor based surface-enhanced raman spectroscopy for the detection of Cd2+ in environmental water samples [J]. Analytical Chemistry, 2014, 86: 12236-12242.
    [24]
    KALLURI J R, ARBNESHI T, AFRINKHAN S, et al. Use of gold nanoparticles in a simple colorimetric and ultrasensitive dynamic light scattering assay: Selective detection of arsenic in groundwater [J]. Angewandte Chemie International Edition, 2009, 48: 9668-9671.
    [25]
    BANERJEE S, KUMAR N P, SRINIVAS A, et al. Core-shell Fe3O4@Au nanocomposite as dual-functional optical probe and potential removal system for arsenic (III) from water[J]. Journal of Hazardous Materials, 2019, 375: 216-223.
    [26]
    CHANDRA V, PARK J, CHUN Y, et al. Water-dispersible magnetite-reduced graphene oxide composites for arsenic removal [J]. ACS Nano, 2010, 4(7): 3979-3986.
    [27]
    BORUAH B S, BISWAS R. Selective detection of arsenic(III) based on colorimetric approach in aqueous medium using functionalized gold nanoparticles unit[J]. Materials Research Express, 2018，5： 015059.)
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