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CN 34-1054/N

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Preparation of hollow CdS/PANI nanocomposite microspheres for photocatalytic hydrogen evolution

  • Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei 230026, China

Cite this:
https://doi.org/10.3969/j.issn.0253-2778.2019.04.007
  • Received Date: 25 April 2018
  • Accepted Date: 27 July 2018
  • Rev Recd Date: 27 July 2018
  • Publish Date: 30 April 2019
    Abstract

  • Abstract

    Hollow CdS/PANI nanocomposite microspheres were successfully synthesized by the polymerization of aniline in the presence of hollow CdS microspheres, which were prepared via “hard core template” approach. The morphology and structures of nanocomposites could be controlled by adjusting the amount of aniline. The as-prepared photocatalysts were characterized by transmission electronic microscope （TEM）, X-ray diffraction (XRD),

    Abstract

    Hollow CdS/PANI nanocomposite microspheres were successfully synthesized by the polymerization of aniline in the presence of hollow CdS microspheres, which were prepared via “hard core template” approach. The morphology and structures of nanocomposites could be controlled by adjusting the amount of aniline. The as-prepared photocatalysts were characterized by transmission electronic microscope （TEM）, X-ray diffraction (XRD),
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    • References(39)
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    CHEN X, LIU L, PETER Y Y, et al. Increasing solar absorption for photocatalysis with black hydrogenated titanium dioxide nanocrystals[J]. Science, 2011, 331(6018): 746-750.
    [4]
    LI Y, FU Z Y, SU B L. Hierarchically structured porous materials for energy conversion and storage [J]. Advanced Functional Materials, 2012, 22(22): 4634-4667.
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    FUJISHIMA A, HONDA K. Electrochemical photolysis of water at a semiconductor electrode [J]. Nature, 1972, 238: 37-38.
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    BATZILL M. Fundamental aspects of surface engineering of transition metal oxide photocatalysts[J]. Energy & Environmental Science, 2011, 4(9): 3275-3286.
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    NI M, LEUNG M K H, LEUNG D Y C, et al. A review and recent developments in photocatalytic water-splitting using TiO2 for hydrogen production [J]. Renewable and Sustainable Energy Reviews, 2007, 11(3): 401-425.
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    MA Y, WANG X, JIA Y, et al. Titanium dioxide-based nanomaterials for photocatalytic fuel generations [J]. Chemical Reviews, 2014, 114(19): 9987-10043.
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    BUTCHER JR D P, GEWIRTH A A. Photoelectrochemical response of TlVO4 and InVO4: TlVO4 composites [J]. Chemistry of Materials, 2010, 22(8): 2555-2562.
    [10]
    IWASE A, KATO H, KUDO A. A simple preparation method of visible-light-driven BiVO4 photocatalysts from oxide starting materials (Bi2O3 and V2O5) and their photocatalytic activities [J]. Journal of Solar Energy Engineering, 2010, 132(2): 1-5.
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    HAN C, YANG M Q, WENG B, et al. Improving the photocatalytic activity and anti-photocorrosion of semiconductor ZnO by coupling with versatile carbon[J]. Physical Chemistry Chemical Physics, 2014, 16(32): 16891-16903.
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    KASAHARA A, NUKUMIZU K, TAKATA T, et al. LaTiO2N as a visible-light (≤600 nm)-driven photocatalyst (2)[J]. The Journal of Physical Chemistry B, 2003, 107(3): 791-797.
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    LUO M, LIU Y, HU J, et al. One-pot synthesis of CdS and Ni-doped CdS hollow spheres with enhanced photocatalytic activity and durability [J]. ACS Applied Materials & Interfaces, 2012, 4(3): 1813-1821.
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    SARANYA M, RAMACHANDRAN R, SAMUEL E J J, et al. Enhanced visible light photocatalytic reduction of organic pollutant and electrochemical properties of CuS catalyst [J]. Powder Technology, 2015, 279: 209-220.
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    MARUSKA H P, GHOSH A K. Photocatalytic decomposition of water at semiconductor electrodes [J]. Solar Energy, 1978, 20(6): 443-458.
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    MATSUMURA M, FURUKAWA S, SAHO Y, et al. Cadmium sulfide photocatalyzed hydrogen production from aqueous solutions of sulfite: Effect of crystal structure and preparation method of the catalyst [J]. The Journal of Physical Chemistry, 1985, 89(8): 1327-1329.
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    MENG A, ZHU B, ZHONG B, et al. Direct Z-scheme TiO2/CdS hierarchical photocatalyst for enhanced photocatalytic H2-production activity [J]. Applied Surface Science, 2017, 422: 518-527.
    [20]
    LI G S, ZHANG D Q, YU J C. A new visible-light photocatalyst: CdS quantum dots embedded mesoporous TiO2 [J]. Environmental Science & Technology, 2009, 43(18): 7079-7085.
    [21]
    XIE Y, ALI G, YOO S H, et al. Sonication-assisted synthesis of CdS quantum-dot-sensitized TiO2 nanotube arrays with enhanced photoelectrochemical and photocatalytic activity [J]. ACS Applied Materials & Interfaces, 2010, 2(10): 2910-2914.
    [22]
    XIAO F X, MIAO J, WANG H Y, et al. Self-assembly of hierarchically ordered CdS quantum dots-TiO2 nanotube array heterostructures as efficient visible light photocatalysts for photoredox applications [J]. Journal of Materials Chemistry A, 2013, 1(39): 12229-12238.
    [23]
    ZHANG S, CHEN Q, JING D, et al. Visible photoactivity and antiphotocorrosion performance of PdS-CdS photocatalysts modified by polyaniline [J]. International Journal of Hydrogen Energy, 2012, 37(1): 791-796.
    [24]
    WANG C, WANG L, JIN J, et al. Probing effective photocorrosion inhibition and highly improved photocatalytic hydrogen production on monodisperse PANI@ CdS core-shell nanospheres [J]. Applied Catalysis B: Environmental, 2016, 188: 351-359.
    [25]
    TRAN H D, LI D, KANER R B. One-dimensional conducting polymer nanostructures: Bulk synthesis and applications[J]. Advanced Materials, 2009, 21(14/15): 1487-1499.
    [26]
    LI X, WANG D, CHENG G, et al. Preparation of polyaniline-modified TiO2 nanoparticles and their photocatalytic activity under visible light illumination [J]. Applied Catalysis B: Environmental, 2008, 81(3/4): 267-273.
    [27]
    LU X, ZHANG W, WANG C, et al. One-dimensional conducting polymer nanocomposites: Synthesis, properties and applications [J]. Progress in Polymer Science, 2011, 36(5): 671-712.
    [28]
    LIAO G, CHEN S, QUAN X, et al. Remarkable improvement of visible light photocatalysis with PANI modified core-shell mesoporous TiO2 microspheres [J]. Applied Catalysis B: Environmental, 2011, 102(1/2): 126-131.
    [29]
    SHANG M, WANG W, SUN S, et al. Efficient visible light-induced photocatalytic degradation of contaminant by spindle-like PANI/BiVO4[J]. The Journal of Physical Chemistry C, 2009, 113(47): 20228-20233.
    [30]
    HU Z A, XIE Y L, WANG Y X, et al. Polyaniline/SnO2 nanocomposite for supercapacitor applications [J]. Materials Chemistry and Physics, 2009, 114(2/3): 990-995.
    [31]
    BALLAV N, BISWAS M. Conductive composites of polyaniline and polypyrrole with MoO3 [J]. Materials Letters, 2006, 60(4): 514-517.
    [32]
    ZHANG H, ZHU Y. Significant visible photoactivity and antiphotocorrosion performance of CdS photocatalysts after monolayer polyaniline hybridization [J]. The Journal of Physical Chemistry C, 2010, 114(13): 5822-5826.
    [33]
    ZHANG Q, LEE I, JOO J B, et al. Core-shell nanostructured catalysts [J]. Accounts of Chemical Research, 2012, 46(8): 1816-1824.
    [34]
    NGUYEN C C, VU N N, DO T O. Recent advances in the development of sunlight-driven hollow structure photocatalysts and their applications [J]. Journal of Materials Chemistry A, 2015, 3(36): 18345-18359.
    [35]
    WANG F W, LIU H R, ZHANG Y, et al. Synthesis of snowman-like polymer-silica asymmetric particles by combination of hydrolytic condensation process with γ-ray radiation initiated seeded emulsion polymerization[J]. Journal of Polymer Science Part A: Polymer Chemistry, 2014, 52(3): 339-348.
    [36]
    张宇, 张俊祥，付德刚，等. 用硫脲分子表面修饰的 CdS 纳米粒子的合成和表征 [J]. 无机化学学报, 1999, 15(5): 595-600.
    ZHANG Yu, ZHANG Junxiang, FU Degang, et al.Synthesis and characterization of the CdS nanoparticles surface-capped with thiourea [J]. Chinese Journal of Inorganic Chemistry, 1999, 15(5): 595-600.
    [37]
    HE K, LI M, GUO L. Preparation and photocatalytic activity of PANI-CdS composites for hydrogen evolution [J]. International Journal of Hydrogen Energy, 2012, 37(1): 755-759.
    [38]
    KAUFMANEN. Characterization of Materials[M].New York: Wiley-Interscience, 2003: 2.
    [39]
    WANG L, WAN Y, DING Y, et al. Conjugated microporous polymer nanosheets for overall water splitting using visible light[J]. Advanced Materials, 2017, 29(38):1702428.)
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    [1]
    MURADOV N Z, VEZIRO?値LU T N. “Green” path from fossil-based to hydrogen economy: An overview of carbon-neutral technologies [J]. International Journal of Hydrogen Energy, 2008, 33(23): 6804-6839.
    [2]
    JOHNSTON B, MAYO M C, KHARE A. Hydrogen: The energy source for the 21st century [J]. Technovation, 2005, 25(6): 569-585.
    [3]
    CHEN X, LIU L, PETER Y Y, et al. Increasing solar absorption for photocatalysis with black hydrogenated titanium dioxide nanocrystals[J]. Science, 2011, 331(6018): 746-750.
    [4]
    LI Y, FU Z Y, SU B L. Hierarchically structured porous materials for energy conversion and storage [J]. Advanced Functional Materials, 2012, 22(22): 4634-4667.
    [5]
    FUJISHIMA A, HONDA K. Electrochemical photolysis of water at a semiconductor electrode [J]. Nature, 1972, 238: 37-38.
    [6]
    BATZILL M. Fundamental aspects of surface engineering of transition metal oxide photocatalysts[J]. Energy & Environmental Science, 2011, 4(9): 3275-3286.
    [7]
    NI M, LEUNG M K H, LEUNG D Y C, et al. A review and recent developments in photocatalytic water-splitting using TiO2 for hydrogen production [J]. Renewable and Sustainable Energy Reviews, 2007, 11(3): 401-425.
    [8]
    MA Y, WANG X, JIA Y, et al. Titanium dioxide-based nanomaterials for photocatalytic fuel generations [J]. Chemical Reviews, 2014, 114(19): 9987-10043.
    [9]
    BUTCHER JR D P, GEWIRTH A A. Photoelectrochemical response of TlVO4 and InVO4: TlVO4 composites [J]. Chemistry of Materials, 2010, 22(8): 2555-2562.
    [10]
    IWASE A, KATO H, KUDO A. A simple preparation method of visible-light-driven BiVO4 photocatalysts from oxide starting materials (Bi2O3 and V2O5) and their photocatalytic activities [J]. Journal of Solar Energy Engineering, 2010, 132(2): 1-5.
    [11]
    HAN C, YANG M Q, WENG B, et al. Improving the photocatalytic activity and anti-photocorrosion of semiconductor ZnO by coupling with versatile carbon[J]. Physical Chemistry Chemical Physics, 2014, 16(32): 16891-16903.
    [12]
    KASAHARA A, NUKUMIZU K, TAKATA T, et al. LaTiO2N as a visible-light (≤600 nm)-driven photocatalyst (2)[J]. The Journal of Physical Chemistry B, 2003, 107(3): 791-797.
    [13]
    LUO M, LIU Y, HU J, et al. One-pot synthesis of CdS and Ni-doped CdS hollow spheres with enhanced photocatalytic activity and durability [J]. ACS Applied Materials & Interfaces, 2012, 4(3): 1813-1821.
    [14]
    LEE G J, ANANDAN S, MASTEN S J, et al. Photocatalytic hydrogen evolution from water splitting using Cu doped ZnS microspheres under visible light irradiation [J]. Renewable Energy, 2016, 89: 18-26.
    [15]
    SARANYA M, RAMACHANDRAN R, SAMUEL E J J, et al. Enhanced visible light photocatalytic reduction of organic pollutant and electrochemical properties of CuS catalyst [J]. Powder Technology, 2015, 279: 209-220.
    [16]
    MARUSKA H P, GHOSH A K. Photocatalytic decomposition of water at semiconductor electrodes [J]. Solar Energy, 1978, 20(6): 443-458.
    [17]
    MATSUMURA M, FURUKAWA S, SAHO Y, et al. Cadmium sulfide photocatalyzed hydrogen production from aqueous solutions of sulfite: Effect of crystal structure and preparation method of the catalyst [J]. The Journal of Physical Chemistry, 1985, 89(8): 1327-1329.
    [18]
    LIU S, ZHANG N, TANG Z R, et al. Synthesis of one-dimensional CdS@TiO2 core-shell nanocomposites photocatalyst for selective redox: The dual role of TiO2 shell [J]. ACS Applied Materials & Interfaces, 2012, 4(11): 6378-6385.
    [19]
    MENG A, ZHU B, ZHONG B, et al. Direct Z-scheme TiO2/CdS hierarchical photocatalyst for enhanced photocatalytic H2-production activity [J]. Applied Surface Science, 2017, 422: 518-527.
    [20]
    LI G S, ZHANG D Q, YU J C. A new visible-light photocatalyst: CdS quantum dots embedded mesoporous TiO2 [J]. Environmental Science & Technology, 2009, 43(18): 7079-7085.
    [21]
    XIE Y, ALI G, YOO S H, et al. Sonication-assisted synthesis of CdS quantum-dot-sensitized TiO2 nanotube arrays with enhanced photoelectrochemical and photocatalytic activity [J]. ACS Applied Materials & Interfaces, 2010, 2(10): 2910-2914.
    [22]
    XIAO F X, MIAO J, WANG H Y, et al. Self-assembly of hierarchically ordered CdS quantum dots-TiO2 nanotube array heterostructures as efficient visible light photocatalysts for photoredox applications [J]. Journal of Materials Chemistry A, 2013, 1(39): 12229-12238.
    [23]
    ZHANG S, CHEN Q, JING D, et al. Visible photoactivity and antiphotocorrosion performance of PdS-CdS photocatalysts modified by polyaniline [J]. International Journal of Hydrogen Energy, 2012, 37(1): 791-796.
    [24]
    WANG C, WANG L, JIN J, et al. Probing effective photocorrosion inhibition and highly improved photocatalytic hydrogen production on monodisperse PANI@ CdS core-shell nanospheres [J]. Applied Catalysis B: Environmental, 2016, 188: 351-359.
    [25]
    TRAN H D, LI D, KANER R B. One-dimensional conducting polymer nanostructures: Bulk synthesis and applications[J]. Advanced Materials, 2009, 21(14/15): 1487-1499.
    [26]
    LI X, WANG D, CHENG G, et al. Preparation of polyaniline-modified TiO2 nanoparticles and their photocatalytic activity under visible light illumination [J]. Applied Catalysis B: Environmental, 2008, 81(3/4): 267-273.
    [27]
    LU X, ZHANG W, WANG C, et al. One-dimensional conducting polymer nanocomposites: Synthesis, properties and applications [J]. Progress in Polymer Science, 2011, 36(5): 671-712.
    [28]
    LIAO G, CHEN S, QUAN X, et al. Remarkable improvement of visible light photocatalysis with PANI modified core-shell mesoporous TiO2 microspheres [J]. Applied Catalysis B: Environmental, 2011, 102(1/2): 126-131.
    [29]
    SHANG M, WANG W, SUN S, et al. Efficient visible light-induced photocatalytic degradation of contaminant by spindle-like PANI/BiVO4[J]. The Journal of Physical Chemistry C, 2009, 113(47): 20228-20233.
    [30]
    HU Z A, XIE Y L, WANG Y X, et al. Polyaniline/SnO2 nanocomposite for supercapacitor applications [J]. Materials Chemistry and Physics, 2009, 114(2/3): 990-995.
    [31]
    BALLAV N, BISWAS M. Conductive composites of polyaniline and polypyrrole with MoO3 [J]. Materials Letters, 2006, 60(4): 514-517.
    [32]
    ZHANG H, ZHU Y. Significant visible photoactivity and antiphotocorrosion performance of CdS photocatalysts after monolayer polyaniline hybridization [J]. The Journal of Physical Chemistry C, 2010, 114(13): 5822-5826.
    [33]
    ZHANG Q, LEE I, JOO J B, et al. Core-shell nanostructured catalysts [J]. Accounts of Chemical Research, 2012, 46(8): 1816-1824.
    [34]
    NGUYEN C C, VU N N, DO T O. Recent advances in the development of sunlight-driven hollow structure photocatalysts and their applications [J]. Journal of Materials Chemistry A, 2015, 3(36): 18345-18359.
    [35]
    WANG F W, LIU H R, ZHANG Y, et al. Synthesis of snowman-like polymer-silica asymmetric particles by combination of hydrolytic condensation process with γ-ray radiation initiated seeded emulsion polymerization[J]. Journal of Polymer Science Part A: Polymer Chemistry, 2014, 52(3): 339-348.
    [36]
    张宇, 张俊祥，付德刚，等. 用硫脲分子表面修饰的 CdS 纳米粒子的合成和表征 [J]. 无机化学学报, 1999, 15(5): 595-600.
    ZHANG Yu, ZHANG Junxiang, FU Degang, et al.Synthesis and characterization of the CdS nanoparticles surface-capped with thiourea [J]. Chinese Journal of Inorganic Chemistry, 1999, 15(5): 595-600.
    [37]
    HE K, LI M, GUO L. Preparation and photocatalytic activity of PANI-CdS composites for hydrogen evolution [J]. International Journal of Hydrogen Energy, 2012, 37(1): 755-759.
    [38]
    KAUFMANEN. Characterization of Materials[M].New York: Wiley-Interscience, 2003: 2.
    [39]
    WANG L, WAN Y, DING Y, et al. Conjugated microporous polymer nanosheets for overall water splitting using visible light[J]. Advanced Materials, 2017, 29(38):1702428.)
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