ISSN 0253-2778

CN 34-1054/N

Open AccessOpen Access JUSTC Article 11 October 2024

Effect of tantalum doping on the microstructure and photoelectrical properties of transparent conductive zinc oxide films

Cite this:
CSTR: 32290.14.JUSTC-2024-0006
https://doi.org/10.52396/JUSTC-2024-0006
More Information
  • Corresponding author: Email Address: eedewang@ustc.edu.cn
  • Accepted Date: 12 July 2024
  • Available Online: 11 October 2024
  • ZnO thin films with varying Ta concentrations were fabricated through magnetron sputtering. The crystallinity and surface morphology of the ZnO films are significantly influenced by the incorporation of Ta, as evidenced by the X-ray diffraction and scanning electron microscopy results. The lattice constants, as determined by X-ray diffraction, contradict the disparity in Ta and Zn ion radii, which is attributed to the impact of interstitial defects. This inconsistency introduces variations in carrier concentration in this experiment compared with prior studies. Subsequent exploration of the luminescent characteristics and emission mechanism of defect levels in Ta-doped ZnO films was conducted through photoluminescence. Furthermore, the factors influencing the bandgap are discussed.
    ZnO thin films with varying Ta concentrations were fabricated through magnetron sputtering. The crystallinity and surface morphology of the ZnO films are significantly influenced by the incorporation of Ta, as evidenced by the X-ray diffraction and scanning electron microscopy results. The lattice constants, as determined by X-ray diffraction, contradict the disparity in Ta and Zn ion radii, which is attributed to the impact of interstitial defects. This inconsistency introduces variations in carrier concentration in this experiment compared with prior studies. Subsequent exploration of the luminescent characteristics and emission mechanism of defect levels in Ta-doped ZnO films was conducted through photoluminescence. Furthermore, the factors influencing the bandgap are discussed.

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    Figure  1.  (a) EDS of Ta-doped ZnO thin films; (b) relationship between Ta content and sputtering power.

    Figure  4.  Surface morphology of ZnO thin films with different Ta contents.

    Figure  2.  XPS spectra of Ta-doped ZnO thin films: (a) full spectrum; (b) Zn 2p peak; (c) Ta 4f peak.

    Figure  3.  (a) XRD of Ta-doped ZnO thin films; (b) relationships between the Ta content and the resistivity, carrier density, and mobility.

    Figure  5.  PL spectra of samples and substrates at different excitation wavelengths: (a) 532 nm, (b) 473 nm, (c) 325 nm, and (d) normalized PL spectrum of (c).

    Figure  6.  (a) (b) (c) (d) (e): Gaussian fitting of the visible light region of ZnO films with different Ta contents; (f) intensity ratios of the blue, green, yellow, and orange emission peaks to the UV emission peaks.

    Figure  7.  (a) Ultraviolet‒visible transmittance spectra; (b) plot of (αhν)2 vs. hν; (c) plot of dT/dE vs. hν; (d) band gaps obtained from the Tauc plots, dT/dE plots, and PL spectra.

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    Faisal M, Ibrahim A A, Harraz F A, et al. SnO2 doped ZnO nanostructures for highly efficient photocatalyst. Journal of Molecular Catalysis A: Chemical, 2015, 397: 19–25. doi: 10.1016/j.molcata.2014.10.027
    [3]
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    [4]
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    [5]
    Paul R, Arulkumar S, Jenifer K, et al. Al-Diffused ZnO Transparent Conducting Oxide Thin Films for Cadmium Telluride Superstrate Solar Cells: A Comprehensive Study. Journal of Electronic Materials, 2023, 52: 130–139. doi: 10.1007/s11664-022-10001-5
    [6]
    Mustaqima M, Liu C. ZnO-based nanostructures for diluted magnetic semiconductor. Turkish Journal of Physics, 2014, 38 (3): 429–441. doi: 10.3906/fiz-1405-17
    [7]
    Chen X X, Yin Z Z, Yan J L, et al. Fabrication of ZnO@Fe2O3 superhydrophobic coatings with high thermal conductivity. Surface and Coatings Technology, 2023, 467: 129701. doi: 10.1016/j.surfcoat.2023.129701
    [8]
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    [9]
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    [10]
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    [12]
    Chang G S, Kurmaev E Z, Boukhvalov D W, et al. Co and Al co-doping for ferromagnetism in ZnO: Co diluted magnetic semiconductors. Journal of Physics: Condensed Matter, 2009, 21 (5): 056002. doi: 10.1088/0953-8984/21/5/056002
    [13]
    Ko H J, Chen Y F, Zhu Z, et al. Photoluminescence properties of ZnO epilayers grown on CaF2(111) by plasma assisted molecular beam epitaxy. Applied Physics Letters, 2000, 76: 1905–1907. doi: 10.1063/1.126207
    [14]
    Belghazi Y, Ait Aouaj M, Yadari M E, et al. Elaboration and characterization of Co-doped ZnO thin films deposited by spray pyrolysis technique. Microelectronics Journal, 2009, 40 (2): 265–267. doi: 10.1016/j.mejo.2008.07.051
    [15]
    Belghazi Y, Schmerber G, Colis S, et al. Room-temperature ferromagnetism in Co-doped ZnO thin films prepared by sol-gel method. Journal of Magnetism and Magnetic Materials, 2007, 310 (2): 2092–2094. doi: 10.1016/j.jmmm.2006.10.1138
    [16]
    Petersen J, Brimont C, Gallart M, et al. Correlation of structural properties with energy transfer of Eu-doped ZnO thin films prepared by sol-gel process and magnetron reactive sputtering. Journal of Applied Physics, 2010, 107: 123522. doi: 10.1063/1.3436628
    [17]
    Deng Y T, Xu F L, Yin Z Z, et al. Controllable fabrication of superhydrophobic alloys surface on 304 stainless steel substrate for anti-icing performance. Ceramics International, 2023, 49 (15): 25135–25143. doi: 10.1016/j.ceramint.2023.05.044
    [18]
    Yuan F, Yin Z Z, Xue M S, et al. A multifunctional and environmentally safe superhydrophobic membrane with superior oil/water separation, photocatalytic degradation and anti-biofouling performance. Journal of Colloid and Interface Science, 2022, 611: 93–104. doi: 10.1016/j.jcis.2021.12.070
    [19]
    Chen X X, Yin Z Z, Chen Z B, et al. Superhydrophobic Photocatalytic Self-Cleaning Nanocellulose-Based Strain Sensor for Full-Range Human Motion Monitoring. Advanced Materials Interfaces, 2023, 10 (33): 2300350. doi: 10.1002/admi.202300350
    [20]
    Janotti A, Van de Walle C G. Native point defects in ZnO. Physical Review B, 2007, 76 (16): 165202. doi: 10.1103/PhysRevB.76.165202
    [21]
    Yang Y H, Chen X Y, Feng Y, et al. Physical Mechanism of Blue-Shift of UV Luminescence of a Single Pencil-Like ZnO Nanowire. Nano Letters, 2007, 7 (12): 3879–3883. doi: 10.1021/nl071849h
    [22]
    Mahmood K, Song D, Park S B. Effects of thermal treatment on the characteristics of boron and tantalum-doped ZnO thin films deposited by the electrospraying method at atmospheric pressure. Surface and Coatings Technology, 2012, 206 (23): 4730–4740. doi: 10.1016/j.surfcoat.2012.01.047
    [23]
    Wu Y H, Li C P, Li M J, et al. Microstructural and optical properties of Ta-doped ZnO films prepared by radio frequency magnetron sputtering. Ceramics International, 2016, 42 (9): 10847–10853. doi: 10.1016/j.ceramint.2016.03.214
    [24]
    Cheng Y L, Cao L, He G, et al. Preparation, microstructure and photoelectrical properties of Tantalum-doped zinc oxide transparent conducting films. Journal of Alloys and Compounds, 2014, 608 (25): 85–89. doi: 10.1016/j.jallcom.2014.03.031
    [25]
    Liu X, Pan K, Li W B, et al. Optical and gas sensing properties of Al-doped ZnO transparent conducting films prepared by sol-gel method under different heat treatments. Ceramics International, 2014, 40 (7): 9931–9939. doi: 10.1016/j.ceramint.2014.02.090
    [26]
    Xu G Q, Shen X K, Hu Y, et al. Fabrication of tantalum oxide layers onto titanium substrates for improved corrosion resistance and cytocompatibility. Surface and Coatings Technology, 2015, 272 (25): 58–65. doi: 10.1016/j.surfcoat.2015.04.024
    [27]
    Su Y G, Lang J Y, Li L P, et al. Unexpected Catalytic Performance in Silent Tantalum Oxide through Nitridation and Defect Chemistry. Journal of the American Chemical Society, 2013, 135 (31): 11433–11436. doi: 10.1021/ja404239z
    [28]
    Wang L W, Wu F, Tian D X, et al. Effects of Na content on structural and optical properties of Na-doped ZnO thin films prepared by sol-gel method. Journal of Alloys and Compounds, 2015, 623 (25): 367–373. doi: 10.1016/j.jallcom.2014.11.055
    [29]
    Lee J H, Song J T. Dependence of the electrical and optical properties on the bias voltage for ZnO: Al films deposited by r. f. magnetron sputtering. Thin Solid Films, 2008, 516 (7): 1377–1381. doi: 10.1016/j.tsf.2007.03.078
    [30]
    Poongodi G, Kumar R M, Jayavel R. Structural, optical and visible light photocatalytic properties of nanocrystalline Nd doped ZnO thin films prepared by spin coating method. Ceramics International, 2015, 41 (3): 4169–4175. doi: 10.1016/j.ceramint.2014.12.098
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