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Ta掺杂对透明导电ZnO薄膜微观结构、光电性能的影响

Effect of tantalum doping on the microstructure and photoelectrical properties of transparent conductive zinc oxide films

  • 摘要: 采用磁控共溅射法制备了不同Ta浓度掺杂的ZnO薄膜。X射线衍射与扫描电子显微镜的结果表明,Ta掺杂对ZnO薄膜结晶性与表面形貌影响很大。同时X射线衍射得到的晶格常数与Ta、Zn离子半径差矛盾,归因于间隙缺陷的影响。这也使得本实验薄膜载流子浓度的变化与以往研究存在一些区别。利用光致发光进一步研究了Ta掺杂ZnO薄膜的发光特性与缺陷能级的发射机制并讨论了带隙的影响因素。

     

    Abstract: ZnO thin films with varying Ta concentrations were fabricated through magnetron sputtering. The crystallinity and surface morphology of the ZnO films are significantly influenced by the incorporation of Ta, as evidenced by the X-ray diffraction and scanning electron microscopy results. The lattice constants, as determined by X-ray diffraction, contradict the disparity in Ta and Zn ion radii, which is attributed to the impact of interstitial defects. This inconsistency introduces variations in carrier concentration in this experiment compared with prior studies. Subsequent exploration of the luminescent characteristics and emission mechanism of defect levels in Ta-doped ZnO films was conducted through photoluminescence. Furthermore, the factors influencing the bandgap are discussed.

     

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