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增强抗冲击和热性能的功能防护复合材料

Advanced functional safeguarding composites with enhanced anti-impact and excellent thermal properties

  • 摘要: 个人安全防护在日常生活中一直扮演着重要的角色。开发具有增强抗冲击和优异热性能的先进功能安全防护复合材料将是防护服的重大发展。因此,通过将短凯夫拉纤维(KFs)引入到剪切变硬弹性体(SSE)中制备了凯夫拉纤维增强聚合物(KFRP)。具有15 wt% KFs的KFRP(KFRP-15%)的储能模量随剪切频率由0.1 Hz到100 Hz从222.8 kPa增加到830.8 kPa。垂直型KFRP-15%相比SSE具有更高的抗拉强度(2.65 MPa)和断裂韧性(11.95 kJ/m2),表现出更强的抗撕裂性。另外,KFRP-15%具有优异的抗冲击性能,它可以将锤头冲击力从1.74 kN耗散到0.56 kN,且在10次连续冲击后仍然保持完好。进一步,KFRP-15%也具有优异的抗刺性能。此外,KFRP-15%还表现出改善的传热性能、阻燃和抑烟能力。最后,集防护、散热和阻燃一体的基于KFRP-15%的护腕被成功制备。

     

    Abstract: Personal safety protection has played an important role in daily life. Developing advanced functional safeguarding composites with enhanced anti-impact and excellent thermal properties will be a significant development for body armor. Herein, Kevlar fiber reinforced polymers (KFRP) were fabricated by introducing short Kevlar fibers (KFs) into a shear stiffening elastomer (SSE). The storage modulus of KFRP with 15 wt% KFs (KFRP-15%) increased from 222.8 kPa to 830.8 kPa when the shear frequency varied from 0.1 Hz to 100 Hz. KFRP-15% achieved a higher tensile strength (2.65 MPa) and fracture toughness (11.95 kJ/m2) than SSE in the vertical type, showing superior tear resistance. Additionally, KFRP-15% exhibited promising anti-impact properties, which could dissipate the drop hammer impact force from 1.74 kN to 0.56 kN and remained intact after 10 consecutive impacts. Moreover, KFRP-15% also presented excellent stab-resistant performance. In addition, KFRP-15% also showed improved heat transfer properties, flame retardancy, and smoke suppression capabilities. Finally, functional bracers based on KFRP-15% for protection, thermal-dissipation, and flame-retardant were successfully prepared.

     

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