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氧化(Fe75Co25)5GeTe2实现的二维室温软磁体

Realizing soft two-dimensional room temperature magnets in oxidized (Fe75Co25)5GeTe2

  • 摘要: 二维范德华(vdW)磁体在自旋电子学器件中展示了令人瞩目的性能,引起了广泛关注,但具有小矫顽场的面内二维软磁体的发展仍然有限。本研究中,我们制备了高质量的(Fe75Co25)5GeTe2晶体,在室温下自然氧化的(Fe75Co25)5GeTe2薄片中实现了约3 Oe矫顽场的面内二维软磁特性。通过结合X射线磁圆二色性(XMCD)和铁磁共振(FMR)技术,揭示了其高达350 K的居里温度和室温下相对较低的磁阻尼。克尔显微镜的结果进一步表明,相较于未氧化的样品,在液氮温度下,氧化样品表现出交换偏置和非常规的矫顽场减小。透射电子显微镜(TEM)和密度泛函理论(DFT)计算结果的详细分析表明,这种现象归因于氧插入引起的磁各向异性和层间交换耦合的改变。这些发现深化了对Co掺杂的Fe5GeTe2家族磁性的理解,并强调了在二维范德华磁体中氧化调制的潜力,将(Fe75Co25)5GeTe2定位为下一代自旋电子器件的有力候选者。

     

    Abstract: Two-dimensional (2D) van der Waals (vdW) magnets have demonstrated intriguing functionalities in spintronic devices and have drawn enormous interest. Nevertheless, the development of soft in-plane 2D magnets with low coercivity remains limited. In this study, we fabricated a high-quality (Fe75Co25)5GeTe2 crystal and achieved a soft in-plane 2D magnet with coercivity of approximately 3 Oe in a naturally oxidized (Fe75Co25)5GeTe2 flake at room temperature. A combination of X-ray magnetic circular dichroism (XMCD) and ferromagnetic resonance (FMR) revealed a high Curie temperature of ~350 K and relatively low magnetic damping at room temperature. Kerr microscopy further demonstrated that the oxidized flakes exhibited exchange bias and an unconventional reduction in coercivity compared with their non-oxidized counterparts at liquid nitrogen temperatures. Detailed analyses using transmission electron microscopy (TEM) and density functional theory (DFT) calculations attribute this behavior to modifications in magnetic anisotropy and interlayer exchange coupling induced by oxygen intercalation. These findings deepen the understanding of the magnetic properties of the cobalt-doped Fe5GeTe2 family and highlight the potential of oxidation modulation in 2D vdW magnets, positioning (Fe75Co25)5GeTe2 as a promising candidate for next-generation spintronic devices.

     

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